DICP OpenIR
Metals (Ni, Fe)-Incorporated Titanate Nanotubes Induced Destabilization of LiBH4
Si, Xiaoliang1,2; Li, Fen1; Sun, Lixian1; Xu, Fen3; Liu, Shusheng1; Zhang, Jian1; Zhu, Min4; Ouyang, Liu-Zhang4; Sun, Dalin5; Liu, Ying-Liang6
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY C
2011-05-19
DOI10.1021/jp111752w
Volume115Issue:19Pages:9780-9786
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
WOS KeywordREVERSIBLE HYDROGEN STORAGE ; LITHIUM BOROHYDRIDE ; HYDRIDES ; DEHYDROGENATION ; DECOMPOSITION ; PERFORMANCES ; DESORPTION ; KINETICS ; RELEASE ; SYSTEMS
AbstractMetals (Ni, Fe)-incorporated titanate nanotubes (M-TNT, M = Ni, Fe) with H2Ti3O7 structure were synthesized to destabilize the LiBH4 for hydrogen storage. The onset temperature of dehydrogenation was reduced to 100 degrees C for LiBH4 and M-TNT composite, which could release 4.5 wt % hydrogen at 120 degrees C and 11 wt % hydrogen at 260 degrees C from LiBH4. Our experiment results indicate that ball-milled LiBH4/Ni TNT sample has a better dehydrogenation performance than ball-milled LiBH4/Ni/H2Ti3O7 nanotube and ball-milled LiBH4/NiO/H2Ti3O7 nanotube samples. Furthermore, one finds that the release of poisoning species like BH3 and B2H6 could be inhibited by nanotube with H2Ti3O7 structure rather than that with anatase structure. The interactions between LiBH4 and different structure nanotubes are investigated by the first-principle calculation in the present work.
Language英语
WOS IDWOS:000290427400060
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142606
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
4.S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
5.Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China
6.Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Si, Xiaoliang,Li, Fen,Sun, Lixian,et al. Metals (Ni, Fe)-Incorporated Titanate Nanotubes Induced Destabilization of LiBH4[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2011,115(19):9780-9786.
APA Si, Xiaoliang.,Li, Fen.,Sun, Lixian.,Xu, Fen.,Liu, Shusheng.,...&Liu, Ying-Liang.(2011).Metals (Ni, Fe)-Incorporated Titanate Nanotubes Induced Destabilization of LiBH4.JOURNAL OF PHYSICAL CHEMISTRY C,115(19),9780-9786.
MLA Si, Xiaoliang,et al."Metals (Ni, Fe)-Incorporated Titanate Nanotubes Induced Destabilization of LiBH4".JOURNAL OF PHYSICAL CHEMISTRY C 115.19(2011):9780-9786.
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