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Crossed Beams Study on the Dynamics of Cl Atom Reaction with Silane
Xiao, Chong-fa; Shen, Guan-lin; Wang, Xiu-yan; Yang, Xue-ming
关键词Chlorine Atom Silane s(n)2 Mechanism Universal Crossed Molecular Beam
刊名CHINESE JOURNAL OF CHEMICAL PHYSICS
2011-02-01
DOI10.1088/1674-0068/24/01/4-7
24期:1页:4-7
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]CHLORINE ; SIH4 ; PATHWAYS
英文摘要The dynamics of the Cl+SiH(4) reaction has been studied using the universal crossed molecular beam method. Angular resolved time-of-flight spectra have been measured for the channel SiH(3)Cl+H. Product angular distributions as well as energy distributions in the center-of-mass frame were determined for the channel. Experimental results show that the SiH(3)Cl product is mainly backward scattered relative to the Cl atom beam direction, suggesting that the channel takes place via a typical S(N)2 type reaction mechanism.
语种英语
WOS记录号WOS:000288641200002
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142608
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
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Xiao, Chong-fa,Shen, Guan-lin,Wang, Xiu-yan,et al. Crossed Beams Study on the Dynamics of Cl Atom Reaction with Silane[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2011,24(1):4-7.
APA Xiao, Chong-fa,Shen, Guan-lin,Wang, Xiu-yan,&Yang, Xue-ming.(2011).Crossed Beams Study on the Dynamics of Cl Atom Reaction with Silane.CHINESE JOURNAL OF CHEMICAL PHYSICS,24(1),4-7.
MLA Xiao, Chong-fa,et al."Crossed Beams Study on the Dynamics of Cl Atom Reaction with Silane".CHINESE JOURNAL OF CHEMICAL PHYSICS 24.1(2011):4-7.
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