中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Photoelectron Imaging of Ag-(H2O)(x) and AgOH-(H2O)(y) (x=1,2, y=0-4)
作者: Chi, Chaoxian1;  Xie, Hua2;  Li, Yuzhen1;  Cong, Ran2;  Zhou, Mingfei1;  Tang, Zichao2
刊名: JOURNAL OF PHYSICAL CHEMISTRY A
发表日期: 2011-06-02
DOI: 10.1021/jp202497x
卷: 115, 期:21, 页:5380-5386
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical ;  Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Chemistry ;  Physics
英文摘要: The photoelectron images of Ag-(H2O)(x) (x = 1,2) and AgOH-(H2O)(y) (y = 0-4) are reported. The Ag-(H2O)(1,2) anionic complexes have similar characteristics to the other two coinage metal-water complexes that can be characterized as metal atomic anion solvated by water molecules with the electron mainly localized on the metal. The vibrationally well-resolved photoelectron spectrum allows the adiabatic detachment energy (ADE) and vertical detachment energy (VDE) of AgOH- to be determined as 1.18(2) and 1.24(2) eV, respectively. The AgOH- anion interacts more strongly with water molecules than the Ag- anion. The photoelectron spectra of Ag-(H2O)(x) and AgOH-(H2O)(y) show a gradual increase in ADE and VDE with increasing x and y due to the solvent stabilization.
关键词[WOS]: TRANSITION-METAL HYDROXIDES ;  EFFECTIVE CORE POTENTIALS ;  CLUSTER NEGATIVE-IONS ;  DER-WAALS COMPLEXES ;  AB-INITIO ;  MOLECULAR CALCULATIONS ;  INFRARED-SPECTROSCOPY ;  ELECTRON-AFFINITIES ;  WEAK-INTERACTIONS ;  WATER CLUSTERS
语种: 英语
WOS记录号: WOS:000290914500017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142618
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysts & Innovat Mat, Shanghai 200433, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Chi, Chaoxian,Xie, Hua,Li, Yuzhen,et al. Photoelectron Imaging of Ag-(H2O)(x) and AgOH-(H2O)(y) (x=1,2, y=0-4)[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2011,115(21):5380-5386.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Chi, Chaoxian]'s Articles
 [Xie, Hua]'s Articles
 [Li, Yuzhen]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Chi, Chaoxian]‘s Articles
 [Xie, Hua]‘s Articles
 [Li, Yuzhen]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace