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Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds
Lin, Mu; Li, Feng; Jiao, Lei; Yu, Zhi-Xiang
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
2011-02-16
DOI10.1021/ja110039h
133期:6页:1690-1693
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]PAUSON-KHAND REACTION ; ATOM ECONOMY ; CARBONYLATIVE CARBOTRICYCLIZATION ; RHODIUM COMPLEXES ; ORGANIC-SYNTHESIS ; ENEDIYNES ; CYCLOPROPANES ; ALKYNES ; VINYLCYCLOPROPANES ; MECHANISM
英文摘要A novel Rh(I)-catalyzed formal [5 + 1]/[2 + 2 + 1] cycloaddition of 1-yne-vinylcydopropanes and two CO units for the construction of multifunctional angular tricyclic 5/5/6 skeletons with one or two adjacent bridgehead quaternary all-carbon stereocenters in one step has been developed. Preliminary density functional theory calculations have been carried out to investigate the reaction mechanism and the substituent effects.
语种英语
WOS记录号WOS:000287831800021
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142626
专题中国科学院大连化学物理研究所
作者单位Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Lin, Mu,Li, Feng,Jiao, Lei,et al. Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2011,133(6):1690-1693.
APA Lin, Mu,Li, Feng,Jiao, Lei,&Yu, Zhi-Xiang.(2011).Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,133(6),1690-1693.
MLA Lin, Mu,et al."Rh(I)-Catalyzed Formal [5+1]/[2+2+1] Cycloaddition of 1-Yne-vinylcyclopropanes and Two CO Units: One-Step Construction of Multifunctional Angular Tricyclic 5/5/6 Compounds".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 133.6(2011):1690-1693.
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