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题名: The Study of Energy Transfer Reaction form He(2(3)S) to CH3Cl and CH3I in a Beam-gas Condition
作者: Li Quanxin1;  Chen Congxiang1;  Ma Xingxiao1;  Li Xuechu2;  Shen Guanlin2
关键词: Beam-gas condition ;  The formation rate constants ;  Available energy ;  Rovibrational distribution
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1994
DOI: 10.3866/PKU.WHXB19941206
卷: 10, 期:12, 页:1081-1086
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The energy transfer readies from lie(VS) to CH3Cl and CH3I have been studied in a beam gas condition by observing the emission of the excited state products. The formation rate constants of CH(A), CH(B) and CH(C) produced by He(2(3)S) with CH3Cl or CH3I were determined. The nascent rovibrational distrbution of CH(A(2)Delta, v(1) = 0 2) anti CH(B-2 Sigma(-), v(1) = 0) from above reactions were obtained by a computer simulation of CH(A - X, B - X) emission. The experimental results showed that the major of the reaction available energies is deposited into the translation energies or the products. The mechanism of the energy transfer reactions from He(2(3)S) to CH3CI and CH3I were also discussed.
语种: 英语
WOS记录号: WOS:000207589900006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142636
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
2.CAS, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Li Quanxin,Chen Congxiang,Ma Xingxiao,et al. The Study of Energy Transfer Reaction form He(2(3)S) to CH3Cl and CH3I in a Beam-gas Condition[J]. ACTA PHYSICO-CHIMICA SINICA,1994,10(12):1081-1086.
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