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题名: Adventure in Asymmetric Hydrogenation: Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics
作者: Hu, Xiang-Ping1;  Wang, Duo-Sheng1;  Yu, Chang-Bin1;  Zhou, Yong-Gui1;  Zheng, Zhuo1;  Ma, SM
关键词: Catalytic asymmetric hydrogenation ;  Chiral phosphorus ligand ;  Iridium ;  Isoquinolines ;  Palladium ;  Quinolines ;  Rhodium
刊名: ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE
发表日期: 2011
DOI: 10.1007/978-3-642-19472-6_10
卷: 36, 页:313-354
收录类别: BSCI ;  SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Catalytic asymmetric hydrogenations of prochiral unsaturated compounds, such as olefins, ketones, and imines, have been intensively studied and are considered as a versatile method of the synthesis of chiral compounds due to atom economy and operational simplicity. Since 2002, we mainly focused on synthesis of new phosphorus ligands, asymmetric hydrogenation of heteroaromatic compounds and palladium-catalyzed asymmetric hydrogenation. Significant contribution was made in the Dalian Institute of Chemical Physics. In this chapter, we hope to share our experience and adventure in the development of chiral monophosphite ligands and phosphine phosphoramidite ligands, asymmetric hydrogenation of heteroaromatic compounds, and the development of new homogeneous palladium catalytic hydrogenation system, which have a wide range of applications in synthesis of chiral compounds.
关键词[WOS]: HIGHLY ENANTIOSELECTIVE HYDROGENATION ;  PHOSPHINE-PHOSPHORAMIDITE LIGANDS ;  IRIDIUM-CATALYZED HYDROGENATION ;  DEHYDROAMINO ACID-DERIVATIVES ;  IR-F-BINAPHANE ;  MONOPHOSPHITE LIGANDS ;  ALPHA-DEHYDROAMINO ;  ORGANOMETALLIC REAGENTS ;  IMINE HYDROGENATION ;  MONOPHOSPHORAMIDITE LIGANDS
语种: 英语
WOS记录号: WOS:000293254500010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142640
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Hu, Xiang-Ping,Wang, Duo-Sheng,Yu, Chang-Bin,et al. Adventure in Asymmetric Hydrogenation: Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics[J]. ASYMMETRIC CATALYSIS FROM A CHINESE PERSPECTIVE,2011,36:313-354.
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