中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C-C and C-N Coupling between Oximines and Alkynes
作者: Zhang, Xingping1, 2;  Chen, Dan2, 3;  Zhao, Miao2;  Zhao, Jing1;  Jia, Aiqun3;  Li, Xingwei2
关键词: alkynes ;  arenes ;  isoquinolines ;  oximines ;  rhodium catalysis
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2011-03-28
DOI: 10.1002/adsc.201000887
卷: 353, 期:5, 页:719-723
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Isoquinolines have been synthesized from the redox-neutral dehydrative C-N and C-C cross-coupling between oximines and alkynes using a catalytic amount of (pentamethylcyclopentadiene)rhodium dichloride dimer {[RhCp*Cl-2](2)} and cesium acetate (CsOAc), a process that involves ortho C-H activation of oximines and subsequent functionalization with alkynes. This redox-neutral catalytic isoquinoline synthesis operates under mild conditions, and is insensitive to moisture or air. A broad scope of coupling partners has been established, and a likely mechanism has been suggested.
关键词[WOS]: PALLADIUM-CATALYZED IMINOANNULATION ;  H BOND-CLEAVAGE ;  INTERNAL ALKYNES ;  TERMINAL ACETYLENES ;  AROMATIC KETIMINES ;  DIRECT ARYLATION ;  ASTERISK-IR ;  ACTIVATION ;  DERIVATIVES ;  PYRIDINES
语种: 英语
WOS记录号: WOS:000288701600008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142653
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Nanjing Univ, Sch Life Sci, State Key Lab Pharmaceut Biotechnol, Nanjing 210093, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210014, Peoples R China

Recommended Citation:
Zhang, Xingping,Chen, Dan,Zhao, Miao,et al. Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C-C and C-N Coupling between Oximines and Alkynes[J]. ADVANCED SYNTHESIS & CATALYSIS,2011,353(5):719-723.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Zhang, Xingping]'s Articles
 [Chen, Dan]'s Articles
 [Zhao, Miao]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Zhang, Xingping]‘s Articles
 [Chen, Dan]‘s Articles
 [Zhao, Miao]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace