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题名: Microstructure evolution of CuInSe2 thin films prepared by single-bath electrodeposition
作者: Ren, Tong1;  Yu, Rui1;  Zhong, Min1;  Shi, Jingying1;  Li, Can1
关键词: Electrodeposition ;  Copper indium selenide ;  Solar cell ;  Microstructure evolution ;  Thin film
刊名: SOLAR ENERGY MATERIALS AND SOLAR CELLS
发表日期: 2011-02-01
DOI: 10.1016/j.solmat.2010.09.011
卷: 95, 期:2, 页:510-520
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Technology ;  Physical Sciences
类目[WOS]: Energy & Fuels ;  Materials Science, Multidisciplinary ;  Physics, Applied
研究领域[WOS]: Energy & Fuels ;  Materials Science ;  Physics
英文摘要: The composition and the microstructure evolutions of CuInSe2 thin films under single-bath electrodeposition processes were investigated. It was found that the film composition was mainly determined by the [Se4+]/[Cu2+] ratios in solution, but the film microstructure is strongly dependent on the initial concentrations of Se4+, Cu2+, and In3+ precursors. Higher initial concentrations of Cu2+ and In3+ in solution are beneficial for the fabrication of compact CuInSe2 thin films with highly crystallized and large grain sized chalcopyrite phase. The microstructure evolution suggests that prior adsorption and reduction of Cu2+ ions and the formation of Cu2Se compound on the substrate can promote the nucleation, growth, and coarsening of CuInSe2 crystal to form a high quality thin film during the electrodeposition processes. (C) 2010 Elsevier B.V. All rights reserved.
关键词[WOS]: COPPER INDIUM DISELENIDE ;  SOLAR-CELLS ;  PHOTOVOLTAIC APPLICATION ;  PRECURSOR LAYERS ;  CU(IN,GA)SE-2 ;  GROWTH ;  MORPHOLOGY ;  ABSORBERS ;  CHEMISTRY
语种: 英语
WOS记录号: WOS:000287006900015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142681
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Ren, Tong,Yu, Rui,Zhong, Min,et al. Microstructure evolution of CuInSe2 thin films prepared by single-bath electrodeposition[J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS,2011,95(2):510-520.
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