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题名: Highly enantioselective asymmetric Darzens reactions with a phase transfer catalyst
作者: Liu, Yan1, 2;  Provencher, Brian A.1;  Bartelson, Keith J.1;  Deng, Li1
刊名: CHEMICAL SCIENCE
发表日期: 2011
DOI: 10.1039/c1sc00137j
卷: 2, 期:7, 页:1301-1304
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A class of easily accessible and readily tunable chiral phase transfer catalysts based on 6'-OH cinchonium salts was found to efficiently catalyze an unprecedented highly enantioselective Darzens reaction of alpha-chloro ketones and aldehydes, which directly produces optically active chiral epoxides from readily available carbonyl compounds.
关键词[WOS]: ALPHA-AMIDO SULFONES ;  AZA-HENRY REACTION ;  CONJUGATE ADDITION ;  CINCHONA ALKALOIDS ;  ALPHA,BETA-UNSATURATED KETONES ;  NONADJACENT STEREOCENTERS ;  ORGANIC CATALYST ;  MICHAEL REACTION ;  GENERAL-METHOD ;  DUAL FUNCTIONS
语种: 英语
WOS记录号: WOS:000291610600013
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142703
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Brandeis Univ, Dept Chem, Waltham, MA 02454 USA
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Liu, Yan,Provencher, Brian A.,Bartelson, Keith J.,et al. Highly enantioselective asymmetric Darzens reactions with a phase transfer catalyst[J]. CHEMICAL SCIENCE,2011,2(7):1301-1304.
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