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Highly enantioselective asymmetric Darzens reactions with a phase transfer catalyst
Liu, Yan1,2; Provencher, Brian A.1; Bartelson, Keith J.1; Deng, Li1
刊名CHEMICAL SCIENCE
2011
DOI10.1039/c1sc00137j
2期:7页:1301-1304
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]ALPHA-AMIDO SULFONES ; AZA-HENRY REACTION ; CONJUGATE ADDITION ; CINCHONA ALKALOIDS ; ALPHA,BETA-UNSATURATED KETONES ; NONADJACENT STEREOCENTERS ; ORGANIC CATALYST ; MICHAEL REACTION ; GENERAL-METHOD ; DUAL FUNCTIONS
英文摘要A class of easily accessible and readily tunable chiral phase transfer catalysts based on 6'-OH cinchonium salts was found to efficiently catalyze an unprecedented highly enantioselective Darzens reaction of alpha-chloro ketones and aldehydes, which directly produces optically active chiral epoxides from readily available carbonyl compounds.
语种英语
WOS记录号WOS:000291610600013
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142703
专题中国科学院大连化学物理研究所
作者单位1.Brandeis Univ, Dept Chem, Waltham, MA 02454 USA
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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Liu, Yan,Provencher, Brian A.,Bartelson, Keith J.,et al. Highly enantioselective asymmetric Darzens reactions with a phase transfer catalyst[J]. CHEMICAL SCIENCE,2011,2(7):1301-1304.
APA Liu, Yan,Provencher, Brian A.,Bartelson, Keith J.,&Deng, Li.(2011).Highly enantioselective asymmetric Darzens reactions with a phase transfer catalyst.CHEMICAL SCIENCE,2(7),1301-1304.
MLA Liu, Yan,et al."Highly enantioselective asymmetric Darzens reactions with a phase transfer catalyst".CHEMICAL SCIENCE 2.7(2011):1301-1304.
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