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DISSOCIATIVE EXCITATION OF CH3NO2 AND CH3OH BY COLLISIONS WITH METASTABLE HELIUM IN THE BEAM EXPERIMENT
YU, HZ; GU, YS; SUN, Q; YIN, YJ; LI, XC; SHEN, GL; WANG, LM
刊名CHEMICAL PHYSICS LETTERS
1994-11-25
230期:3页:243-248
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]ATOMS
英文摘要Dissociative excitation of CH3NO2 and CH3OH by collisions with He (2 3S) has been studied by observing CH(A 2DELTA-X 2PI(r), B 2SIGMA(-)-X 2PI(r), C 2SIGMA+-X 2PI(r)), OH(A 2SIGMA-X 2PI) and H(Balmer) emissions in the beam apparatus. The emission rate constants were determined. The mascent rovibrational distributions of CH(A, upsilon' = 0-2) were obtained by means of computer simulation. The dissociative process and the formation mechanism of CH(A) and H* were studied. A two-body dissociation process through intermediate CH3* for CH(A) was suggested.
语种英语
WOS记录号WOS:A1994PT71800006
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142708
专题中国科学院大连化学物理研究所
作者单位1.SHANDONG UNIV,DEPT CHEM,JINAN 250100,PEOPLES R CHINA
2.DALIAN INST CHEM PHYS CAS,STATE KEY LAB MOLEC REACT DYNAM,DALIAN 116023,PEOPLES R CHINA
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YU, HZ,GU, YS,SUN, Q,et al. DISSOCIATIVE EXCITATION OF CH3NO2 AND CH3OH BY COLLISIONS WITH METASTABLE HELIUM IN THE BEAM EXPERIMENT[J]. CHEMICAL PHYSICS LETTERS,1994,230(3):243-248.
APA YU, HZ.,GU, YS.,SUN, Q.,YIN, YJ.,LI, XC.,...&WANG, LM.(1994).DISSOCIATIVE EXCITATION OF CH3NO2 AND CH3OH BY COLLISIONS WITH METASTABLE HELIUM IN THE BEAM EXPERIMENT.CHEMICAL PHYSICS LETTERS,230(3),243-248.
MLA YU, HZ,et al."DISSOCIATIVE EXCITATION OF CH3NO2 AND CH3OH BY COLLISIONS WITH METASTABLE HELIUM IN THE BEAM EXPERIMENT".CHEMICAL PHYSICS LETTERS 230.3(1994):243-248.
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