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题名: Photodissociation of HOD via the (C)over-tilde(1)B(1) State: OD/OH Branching Ratio and OD Bond Dissociation Energy
作者: Cheng, Li-na1;  Cheng, Yuan1;  Yuan, Kai-jun1;  Guo, Qing1;  Wang, Tao1;  Dai, Dong-xu1;  Yang, Xue-ming1
关键词: Photodissociation ;  Rydberg tagging ;  Branching ratio ;  Dissociation energy
刊名: CHINESE JOURNAL OF CHEMICAL PHYSICS
发表日期: 2011-04-01
DOI: 10.1088/1674-0068/24/02/129-133
卷: 24, 期:2, 页:129-133
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Physics, Atomic, Molecular & Chemical
研究领域[WOS]: Physics
英文摘要: Photodissociation of jet-cooled HOD via the (C) over tilde state around 124 nm has been studied using the H(D)-atom Rydberg tagging time-of-flight technique. Rotational state resolved action spectrum and the product translational energy distribution spectra have been recorded for both D+OH and H+OD dissociation channels. Product channel OH/OD branching ratios for the individual (C) over tilde-(X) over tilde rotational transition have been determined. A comparison is also given with the (B) over tilde-(X) over tilde and (A) over tilde-(X) over tilde transitions. In addition, the dissociation energy of the OD bond in HOD has been determined accurately to be 41751.3 +/- 5 cm(-1).
关键词[WOS]: MULTIPHOTON IONIZATION SPECTROSCOPY ;  121.6 NM ;  PREDISSOCIATION DYNAMICS ;  H2O ;  WATER ;  D2O ;  PATHWAYS ;  PRODUCT ;  PICTURE
语种: 英语
WOS记录号: WOS:000290478500002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142732
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Cheng, Li-na,Cheng, Yuan,Yuan, Kai-jun,et al. Photodissociation of HOD via the (C)over-tilde(1)B(1) State: OD/OH Branching Ratio and OD Bond Dissociation Energy[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2011,24(2):129-133.
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