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LASER-INDUCED FLUORESCENT STUDY OF NASCENT STATE DISTRIBUTION OF THE PRODUCTS FOR Ca+NF3, CHF3 REACTIONS
Wang Jue; Xu Dali; He Guozhong; Lou Nanquan
刊名ACTA PHYSICO-CHIMICA SINICA
1987
DOI10.3866/PKU.WHXB19870210
3期:2页:162-169
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要The state population distributions of the nascent products for Ca+NF3 -> CaF+NF2 and Ca+CHF3 -> CaF+CHF2 reactions were studied by means of LIF in a beam-gas arrangement. From the LIF spectra of CaF and the computer simulations, the CaF vibrational distributions for both reactions were found to be similar to the Boltzmann distribution and the internal energy disposal of CaF was determined quantitatively. The results of the spectral simulation and the information theory computation indicate that NF2 and CHF2 radicals were vibrationally and rotationally excited. These tow reactions are thought to be direct collision reactions with the "late" exoeergicity on potential surface.
语种英语
WOS记录号WOS:000207569200010
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被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142742
专题中国科学院大连化学物理研究所
作者单位Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China
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Wang Jue,Xu Dali,He Guozhong,et al. LASER-INDUCED FLUORESCENT STUDY OF NASCENT STATE DISTRIBUTION OF THE PRODUCTS FOR Ca+NF3, CHF3 REACTIONS[J]. ACTA PHYSICO-CHIMICA SINICA,1987,3(2):162-169.
APA Wang Jue,Xu Dali,He Guozhong,&Lou Nanquan.(1987).LASER-INDUCED FLUORESCENT STUDY OF NASCENT STATE DISTRIBUTION OF THE PRODUCTS FOR Ca+NF3, CHF3 REACTIONS.ACTA PHYSICO-CHIMICA SINICA,3(2),162-169.
MLA Wang Jue,et al."LASER-INDUCED FLUORESCENT STUDY OF NASCENT STATE DISTRIBUTION OF THE PRODUCTS FOR Ca+NF3, CHF3 REACTIONS".ACTA PHYSICO-CHIMICA SINICA 3.2(1987):162-169.
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