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题名: LASER-INDUCED FLUORESCENT STUDY OF NASCENT STATE DISTRIBUTION OF THE PRODUCTS FOR Ca+NF3, CHF3 REACTIONS
作者: Wang Jue1;  Xu Dali1;  He Guozhong1;  Lou Nanquan1
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1987
DOI: 10.3866/PKU.WHXB19870210
卷: 3, 期:2, 页:162-169
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The state population distributions of the nascent products for Ca+NF3 -> CaF+NF2 and Ca+CHF3 -> CaF+CHF2 reactions were studied by means of LIF in a beam-gas arrangement. From the LIF spectra of CaF and the computer simulations, the CaF vibrational distributions for both reactions were found to be similar to the Boltzmann distribution and the internal energy disposal of CaF was determined quantitatively. The results of the spectral simulation and the information theory computation indicate that NF2 and CHF2 radicals were vibrationally and rotationally excited. These tow reactions are thought to be direct collision reactions with the "late" exoeergicity on potential surface.
语种: 英语
WOS记录号: WOS:000207569200010
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142742
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Dalian Inst Chem Phys, Dalian, Peoples R China

Recommended Citation:
Wang Jue,Xu Dali,He Guozhong,et al. LASER-INDUCED FLUORESCENT STUDY OF NASCENT STATE DISTRIBUTION OF THE PRODUCTS FOR Ca+NF3, CHF3 REACTIONS[J]. ACTA PHYSICO-CHIMICA SINICA,1987,3(2):162-169.
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