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题名: Dissociative Excitation of CH3NO2 by Collisions with HE(2(3)S) and Ne(P-3(0.2))
作者: Yu Huazhong1;  Wang Liming1;  Li Xuechu1;  Gu Yueshu1;  Sun Qi1;  Yin Yongjia1
关键词: Dissociative excitation ;  Emission rate ;  Rovibrational population
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1995
DOI: 10.3866/PKU.WHXB19950206
卷: 11, 期:2, 页:123-130
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Dissociative excitation of CH3NO2 by collision with He(2(3)S) and Ne(P-3(0.2)) has been studied respectively by observing CH(A(2) Delta -> X-2 Pi, B-2 Sigma -> X-2 Pi) and C-2 Sigma -> X-2 Pi and H (Balmer) (only in the He(2(3)S)/CH3NO2 reaction) emissions in the beam apparatus under single collision. The emission rate constants of A - X, B X and C - X of CH and H produced from the He(2(3)S)/CH3NO2 reaction were determined by using the reference reaction method. The nascent vibrational distributions and rotational temperatures of CH(A) were determined through computer simulation assumming a Boltzmann rotational distribution. The dissociative process and the formation mechanism of CH(A) were studied, and a two-body dissociative process through an intermediate CH3* for CH(A) was suggested.
语种: 英语
WOS记录号: WOS:000207590100006
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142744
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China

Recommended Citation:
Yu Huazhong,Wang Liming,Li Xuechu,et al. Dissociative Excitation of CH3NO2 by Collisions with HE(2(3)S) and Ne(P-3(0.2))[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(2):123-130.
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