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题名: A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd
作者: Xin Mei1;  Zhai Runsheng1;  Zhang Linhu1;  Guo Xiexian1
关键词: Adsorption ;  Desorption ;  Exchange ;  Kinetics
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1995
DOI: 10.3866/PKU.WHXB19950108
卷: 11, 期:1, 页:38-45
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The kinetics of CO desorption on Pd(111) has been studied by using isotope switch method under the gas-phase pressures of single isotope and mixed ones. The experiments show that the desorption kinetics is non-linear and is first order plus second order on the saturated surface. Based on the delocalized chemisorption model and gas-surface exchange mechanism, the analytic expressions for the desorption kinetics are derived and a dynamic reasoning of the non-linear kinetics has been described in detail.
语种: 英语
WOS记录号: WOS:000207590000008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142749
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

Recommended Citation:
Xin Mei,Zhai Runsheng,Zhang Linhu,et al. A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(1):38-45.
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