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A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd
Xin Mei; Zhai Runsheng; Zhang Linhu; Guo Xiexian
关键词Adsorption Desorption Exchange Kinetics
刊名ACTA PHYSICO-CHIMICA SINICA
1995
DOI10.3866/PKU.WHXB19950108
11期:1页:38-45
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要The kinetics of CO desorption on Pd(111) has been studied by using isotope switch method under the gas-phase pressures of single isotope and mixed ones. The experiments show that the desorption kinetics is non-linear and is first order plus second order on the saturated surface. Based on the delocalized chemisorption model and gas-surface exchange mechanism, the analytic expressions for the desorption kinetics are derived and a dynamic reasoning of the non-linear kinetics has been described in detail.
语种英语
WOS记录号WOS:000207590000008
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142749
专题中国科学院大连化学物理研究所
作者单位Acad Sinica, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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Xin Mei,Zhai Runsheng,Zhang Linhu,et al. A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(1):38-45.
APA Xin Mei,Zhai Runsheng,Zhang Linhu,&Guo Xiexian.(1995).A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd.ACTA PHYSICO-CHIMICA SINICA,11(1),38-45.
MLA Xin Mei,et al."A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd".ACTA PHYSICO-CHIMICA SINICA 11.1(1995):38-45.
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