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题名: Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)
作者: Li Sheng1;  Li Ying1;  Wang Xiaohui1;  Ding Chuanfan2;  Chen Wenwu2;  Gao Yiqin2;  Wang Dianxun1
关键词: Hel photoelectron spectroscopy (PES) ;  Trimethyl borate ;  MNDO calculation
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1996
DOI: 10.3866/PKU.WHXB19960712
卷: 12, 期:7, 页:641-643
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: Hel photoelectron sportrum of B(OCH3)(3) is presented in this rumen The assignment of the spectrum has been also done by an analysis of the intensity of the spectrum bands and the optimized MNDO molecular orbital calculation on B(OCH3)(3) molecule. The split showing a 1.08eV of the bands at the lowest two ionization potentials (IPs) was assigned to the Jahn-Teller split or the doubly degenerate oxygen lone-pair orbitals, And the splits showing 0.42eV and 0.380eV on the above-mentioned bands were considered as the result of spin-orbital interaction Therefore the tins PES study provides an exceedingly experimental example to testify the Jahn-Teller effect and the spin-orbital interaction splitting.
语种: 英语
WOS记录号: WOS:000207600000012
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142783
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Acad Sinica, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
2.Acad Sinica, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China

Recommended Citation:
Li Sheng,Li Ying,Wang Xiaohui,et al. Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)[J]. ACTA PHYSICO-CHIMICA SINICA,1996,12(7):641-643.
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