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Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)
Li Sheng1; Li Ying1; Wang Xiaohui1; Ding Chuanfan2; Chen Wenwu2; Gao Yiqin2; Wang Dianxun1
关键词Hel Photoelectron Spectroscopy (Pes) Trimethyl Borate Mndo Calculation
刊名ACTA PHYSICO-CHIMICA SINICA
1996
DOI10.3866/PKU.WHXB19960712
12期:7页:641-643
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical
研究领域[WOS]Chemistry
英文摘要Hel photoelectron sportrum of B(OCH3)(3) is presented in this rumen The assignment of the spectrum has been also done by an analysis of the intensity of the spectrum bands and the optimized MNDO molecular orbital calculation on B(OCH3)(3) molecule. The split showing a 1.08eV of the bands at the lowest two ionization potentials (IPs) was assigned to the Jahn-Teller split or the doubly degenerate oxygen lone-pair orbitals, And the splits showing 0.42eV and 0.380eV on the above-mentioned bands were considered as the result of spin-orbital interaction Therefore the tins PES study provides an exceedingly experimental example to testify the Jahn-Teller effect and the spin-orbital interaction splitting.
语种英语
WOS记录号WOS:000207600000012
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142783
专题中国科学院大连化学物理研究所
作者单位1.Acad Sinica, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China
2.Acad Sinica, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China
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Li Sheng,Li Ying,Wang Xiaohui,et al. Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)[J]. ACTA PHYSICO-CHIMICA SINICA,1996,12(7):641-643.
APA Li Sheng.,Li Ying.,Wang Xiaohui.,Ding Chuanfan.,Chen Wenwu.,...&Wang Dianxun.(1996).Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3).ACTA PHYSICO-CHIMICA SINICA,12(7),641-643.
MLA Li Sheng,et al."Het Photoelectron Spectroscopic Study of the Electronic Structure on B(OCH3)(3)".ACTA PHYSICO-CHIMICA SINICA 12.7(1996):641-643.
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