DICP OpenIR
Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor
Liu, CQ; Xu, Y; Liao, SJ; Yu, DR; Zhao, YK; Fan, YH
KeywordCatalytic Hollow-fiber Reactor Selective Hydrogenation Propadiene And Propyne Propene Polymer Anchored Palladium Catalyst
Source PublicationJOURNAL OF MEMBRANE SCIENCE
1997-12-24
Volume137Issue:1-2Pages:139-144
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Technology ; Physical Sciences
WOS SubjectEngineering, Chemical ; Polymer Science
WOS Research AreaEngineering ; Polymer Science
WOS KeywordMEMBRANE REACTOR ; PERVAPORATION
AbstractThree catalytic membrane reactors have been established with catalytic hollow fibers prepared by supporting polymer anchored palladium catalyst on the inside wall of three kinds of cellulose acetate (CA) hollow fibers. The selective hydrogenation of propadiene and propyne (C3H4) in propene was carried out using the catalytic membrane reactors at 40 degrees C under 0.1 MPa. In the membrane reactor established with the PVP-Pd/CA-II (PVP=polyvinylpyrrolidone) catalytic hollow fibers, the contents of propadiene and propyne were reduced to <10 and <5 ppm, respectively, and simultaneously a selectivity for propene of 97.8% was obtained. The behavior of the catalytic hollow-fiber reactor was compared with that of the conventional reactor and the influences of some reaction parameters have been studied. (C) 1997 Elsevier Science B.V.
Language英语
WOS IDWOS:000071396900013
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142790
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Liaoning Normal Univ, Dept Chem, Dalian 116021, Peoples R China
Recommended Citation
GB/T 7714
Liu, CQ,Xu, Y,Liao, SJ,et al. Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor[J]. JOURNAL OF MEMBRANE SCIENCE,1997,137(1-2):139-144.
APA Liu, CQ,Xu, Y,Liao, SJ,Yu, DR,Zhao, YK,&Fan, YH.(1997).Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor.JOURNAL OF MEMBRANE SCIENCE,137(1-2),139-144.
MLA Liu, CQ,et al."Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor".JOURNAL OF MEMBRANE SCIENCE 137.1-2(1997):139-144.
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