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Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor
Liu, CQ; Xu, Y; Liao, SJ; Yu, DR; Zhao, YK; Fan, YH
关键词Catalytic Hollow-fiber Reactor Selective Hydrogenation Propadiene And Propyne Propene Polymer Anchored Palladium Catalyst
刊名JOURNAL OF MEMBRANE SCIENCE
1997-12-24
137期:1-2页:139-144
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Technology ; Physical Sciences
类目[WOS]Engineering, Chemical ; Polymer Science
研究领域[WOS]Engineering ; Polymer Science
关键词[WOS]MEMBRANE REACTOR ; PERVAPORATION
英文摘要Three catalytic membrane reactors have been established with catalytic hollow fibers prepared by supporting polymer anchored palladium catalyst on the inside wall of three kinds of cellulose acetate (CA) hollow fibers. The selective hydrogenation of propadiene and propyne (C3H4) in propene was carried out using the catalytic membrane reactors at 40 degrees C under 0.1 MPa. In the membrane reactor established with the PVP-Pd/CA-II (PVP=polyvinylpyrrolidone) catalytic hollow fibers, the contents of propadiene and propyne were reduced to <10 and <5 ppm, respectively, and simultaneously a selectivity for propene of 97.8% was obtained. The behavior of the catalytic hollow-fiber reactor was compared with that of the conventional reactor and the influences of some reaction parameters have been studied. (C) 1997 Elsevier Science B.V.
语种英语
WOS记录号WOS:000071396900013
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142790
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Liaoning Normal Univ, Dept Chem, Dalian 116021, Peoples R China
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Liu, CQ,Xu, Y,Liao, SJ,et al. Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor[J]. JOURNAL OF MEMBRANE SCIENCE,1997,137(1-2):139-144.
APA Liu, CQ,Xu, Y,Liao, SJ,Yu, DR,Zhao, YK,&Fan, YH.(1997).Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor.JOURNAL OF MEMBRANE SCIENCE,137(1-2),139-144.
MLA Liu, CQ,et al."Selective hydrogenation of propadiene and propyne in propene with catalytic polymeric hollow-fiber reactor".JOURNAL OF MEMBRANE SCIENCE 137.1-2(1997):139-144.
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