中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: The Photoionization Investigations of van der Weals Cluster ArHCl
作者: Li Yue1;  Wang Xiuyan1;  Zhang Xiaoguang1;  Li Lianbin1;  Lou Nanquan1;  Seng Liusi2;  Zhang Yunwu2
关键词: Clusters ;  Synchrotron radiation ;  Photoionication
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 1997
DOI: 10.3866/PKU.WHXB19970408
卷: 13, 期:4, 页:322-327
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Physical
研究领域[WOS]: Chemistry
英文摘要: The photoionization processes of van der Waals (vdW) cluster ArHCl in a molecular beam have been investigated by using synchrotron radiation light source and photoionization mass spectrometer. The results show that the concentration of the ArHCl dimer is approximately given by the equation: alpha(ArHCl)%=1.79x10(-8)p(o)(1.5). The PIE curve of ArHCl has been given for the first time. The appearance potential of ArHCl+ is determined to be 12.52 +/- 0.03eV. Using the IP values of HCl obtained in our experiment, the bond dissociation energy of ArHCl+ is deduced to be 0.22 +/- 0.03eV. The theoretical calculations using Gaussian-94w indicate that the value is about 0.16eV. When Ar in the cluster is ionized, the intensity of ArHCl+ is obviously lower than that expected. It indicates that the charge transfer and dissociation processes have taken place in the system.
语种: 英语
WOS记录号: WOS:000207601400008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142821
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230026, Peoples R China

Recommended Citation:
Li Yue,Wang Xiuyan,Zhang Xiaoguang,et al. The Photoionization Investigations of van der Weals Cluster ArHCl[J]. ACTA PHYSICO-CHIMICA SINICA,1997,13(4):322-327.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Li Yue]'s Articles
 [Wang Xiuyan]'s Articles
 [Zhang Xiaoguang]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Li Yue]‘s Articles
 [Wang Xiuyan]‘s Articles
 [Zhang Xiaoguang]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace