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题名: Inhibition of gas-phase oxidation of ethylene in the oxidative conversion of methane and ethane over CaO, La2O3/CaO and SrO-La2O3/CaO catalysts
作者: Yu, L;  Li, WZ;  Ducarme, V;  Mirodatos, C;  Martin, GA
关键词: methane coupling ;  ethane dehydrogenation ;  ethylene oxidation ;  calcium oxide ;  lanthana ;  strontium oxide
刊名: APPLIED CATALYSIS A-GENERAL
发表日期: 1998-12-14
卷: 175, 期:1-2, 页:173-179
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Life Sciences & Biomedicine
类目[WOS]: Chemistry, Physical ;  Environmental Sciences
研究领域[WOS]: Chemistry ;  Environmental Sciences & Ecology
英文摘要: The conversion of methane, ethane and ethylene has been investigated either in an empty reactor or in the presence of a series of calcium-based catalysts including unpromoted calcium oxide (C), calcium oxide promoted with lanthane (LC) and with both lanthana and strontium oxide (SLC). It was found that these solids inhibit the gas-phase oxidation of ethylene, probably by trapping chain-carrier radicals. At T>1000 K, the inhibiting effectiveness varies in the order C
关键词[WOS]: LANTHANUM OXIDE ;  HYDROCARBONS ;  C-2
语种: 英语
WOS记录号: WOS:000077813600017
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142831
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France
2.Sichuan Univ, Dept Chem, Chengdu 610064, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Yu, L,Li, WZ,Ducarme, V,et al. Inhibition of gas-phase oxidation of ethylene in the oxidative conversion of methane and ethane over CaO, La2O3/CaO and SrO-La2O3/CaO catalysts[J]. APPLIED CATALYSIS A-GENERAL,1998,175(1-2):173-179.
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