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Synthesis and dehydrogenation of LiCa(NH2)(3)(BH3)(2)
Liu, Bin1,2; Chua, Yong Shen1; Wu, Guotao1; Xiong, Zhitao1; Chen, Ping1
关键词Calcium Amidoborane Lithium Amide Lica(Nh2)(3)(Bh3)(2) Dehydrogenation
刊名INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2012-06-01
DOI10.1016/j.ijhydene.2012.02.112
37期:11页:9076-9081
收录类别SCI
文章类型Article
类目[WOS]Chemistry, Physical ; Electrochemistry ; Energy & Fuels
研究领域[WOS]Chemistry ; Electrochemistry ; Energy & Fuels
关键词[WOS]HYDROGEN STORAGE PROPERTIES ; N-H COMPOUNDS ; AMMONIA-BORANE ; THERMAL-DECOMPOSITION ; AMIDOBORANES ; NITRIDES ; CATALYST ; RELEASE ; LITHIUM ; IMIDES
英文摘要We report the synthesis of a new hydrogen storage material with a composition of LiCa(NH2)(3)(BH3)(2). The theoretical hydrogen capacity of LiCa(NH2)(3)(BH3)(2) is 9.85 wt.%. It can be prepared by ball milling the mixture of calcium amidoborane (Ca(NH2BH3)(2)) and lithium amide (LiNH2) in a molar ratio of 1:1. The experimental results show that this material starts to release hydrogen at a temperature as low as ca. 50 degrees C, which is ca. 70 degrees C lower than that of pure Ca(NH2BH3)(2) possibly resulting from the active interaction of NH2- in LiNH2 with BH3 in Ca(NH2BH3)(2). ca. 4.1 equiv. or 6.8 wt.% hydrogen can be released at 300 degrees C. The dehydrogenation is a mildly exothermic process forming stable nitride products. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000304976300017
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142840
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Peoples R China
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GB/T 7714
Liu, Bin,Chua, Yong Shen,Wu, Guotao,et al. Synthesis and dehydrogenation of LiCa(NH2)(3)(BH3)(2)[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2012,37(11):9076-9081.
APA Liu, Bin,Chua, Yong Shen,Wu, Guotao,Xiong, Zhitao,&Chen, Ping.(2012).Synthesis and dehydrogenation of LiCa(NH2)(3)(BH3)(2).INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,37(11),9076-9081.
MLA Liu, Bin,et al."Synthesis and dehydrogenation of LiCa(NH2)(3)(BH3)(2)".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 37.11(2012):9076-9081.
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