DICP OpenIR
Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme
Wang, Changhao1,2; Li, Yinghao1,2; Jia, Guoqing1; Liu, Yan1; Lu, Shengmei1; Li, Can1
Source PublicationCHEMICAL COMMUNICATIONS
2012
DOI10.1039/c2cc31320k
Volume48Issue:50Pages:6232-6234
Indexed BySCI
SubtypeArticle
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordBIS(OXAZOLINYL)PYRIDINE-SCANDIUM(III) TRIFLATE COMPLEXES ; INTRAMOLECULAR G-QUADRUPLEX ; K+ SOLUTION ; ASYMMETRIC CATALYSIS ; DEFICIENT CONDITIONS ; ALKYLATION ; SEQUENCE ; PYRROLES ; FORMS
AbstractA human telomeric G-quadruplex (G4DNA) metalloenzyme, assembled with G4DNA and Cu2+ ions, can catalyze the enantioselective Friedel-Crafts (F-C) reaction in water with good enantioselectivity (up to 75% ee). Furthermore, we found that the absolute configuration and the enantioselectivity of the product largely depend on the conformation and the sequence of G4DNA.
Language英语
WOS IDWOS:000304486800007
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142848
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Changhao,Li, Yinghao,Jia, Guoqing,et al. Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme[J]. CHEMICAL COMMUNICATIONS,2012,48(50):6232-6234.
APA Wang, Changhao,Li, Yinghao,Jia, Guoqing,Liu, Yan,Lu, Shengmei,&Li, Can.(2012).Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme.CHEMICAL COMMUNICATIONS,48(50),6232-6234.
MLA Wang, Changhao,et al."Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme".CHEMICAL COMMUNICATIONS 48.50(2012):6232-6234.
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