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题名: Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme
作者: Wang, Changhao1, 2;  Li, Yinghao1, 2;  Jia, Guoqing1;  Liu, Yan1;  Lu, Shengmei1;  Li, Can1
刊名: CHEMICAL COMMUNICATIONS
发表日期: 2012
DOI: 10.1039/c2cc31320k
卷: 48, 期:50, 页:6232-6234
收录类别: SCI
文章类型: Article
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: A human telomeric G-quadruplex (G4DNA) metalloenzyme, assembled with G4DNA and Cu2+ ions, can catalyze the enantioselective Friedel-Crafts (F-C) reaction in water with good enantioselectivity (up to 75% ee). Furthermore, we found that the absolute configuration and the enantioselectivity of the product largely depend on the conformation and the sequence of G4DNA.
关键词[WOS]: BIS(OXAZOLINYL)PYRIDINE-SCANDIUM(III) TRIFLATE COMPLEXES ;  INTRAMOLECULAR G-QUADRUPLEX ;  K+ SOLUTION ;  ASYMMETRIC CATALYSIS ;  DEFICIENT CONDITIONS ;  ALKYLATION ;  SEQUENCE ;  PYRROLES ;  FORMS
语种: 英语
WOS记录号: WOS:000304486800007
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142848
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Wang, Changhao,Li, Yinghao,Jia, Guoqing,et al. Enantioselective Friedel-Crafts reactions in water catalyzed by a human telomeric G-quadruplex DNA metalloenzyme[J]. CHEMICAL COMMUNICATIONS,2012,48(50):6232-6234.
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