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Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions
Zhang, Yalei1,3; Shen, Zheng1,2,3; Zhou, Xuefei1,3; Zhang, Min3; Jin, Fangmin1
刊名GREEN CHEMISTRY
2012
DOI10.1039/c2gc36153a
14期:12页:3285-3288
收录类别SCI
文章类型Article
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]SUPERCRITICAL WATER ; CONVERSION ; BIODIESEL ; OIL ; OXIDATION ; BIOMASS ; TRANSESTERIFICATION ; GENERATION ; CHEMICALS ; CATALYSTS
英文摘要To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with H-1-NMR, H-2-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.
语种英语
WOS记录号WOS:000311413200009
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142861
专题中国科学院大连化学物理研究所
作者单位1.Tongji Univ, Coll Environm Sci & Engn, Key Lab Yangtze River Water Environm MOE, State Key Lab Pollut Control & Resources Reuse, Shanghai 200092, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Tongji Univ, Inst Modern Agr Sci & Engn, Natl Engn Res Ctr Facil Agr, Shanghai 200092, Peoples R China
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GB/T 7714
Zhang, Yalei,Shen, Zheng,Zhou, Xuefei,et al. Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions[J]. GREEN CHEMISTRY,2012,14(12):3285-3288.
APA Zhang, Yalei,Shen, Zheng,Zhou, Xuefei,Zhang, Min,&Jin, Fangmin.(2012).Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions.GREEN CHEMISTRY,14(12),3285-3288.
MLA Zhang, Yalei,et al."Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions".GREEN CHEMISTRY 14.12(2012):3285-3288.
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