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题名: Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions
作者: Zhang, Yalei1, 3;  Shen, Zheng1, 2, 3;  Zhou, Xuefei1, 3;  Zhang, Min3;  Jin, Fangmin1
刊名: GREEN CHEMISTRY
发表日期: 2012
DOI: 10.1039/c2gc36153a
卷: 14, 期:12, 页:3285-3288
收录类别: SCI
文章类型: Article
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: To discover the reaction mechanism for the production of hydrogen and lactic acid from glycerol under alkaline hydrothermal conditions, we identified the different intermediates involved during reactions by investigating the solvent isotope effect with H-1-NMR, H-2-NMR, LC-MS and Gas-MS analyses, and then proposed and proved a potential reaction mechanism.
关键词[WOS]: SUPERCRITICAL WATER ;  CONVERSION ;  BIODIESEL ;  OIL ;  OXIDATION ;  BIOMASS ;  TRANSESTERIFICATION ;  GENERATION ;  CHEMICALS ;  CATALYSTS
语种: 英语
WOS记录号: WOS:000311413200009
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142861
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Tongji Univ, Coll Environm Sci & Engn, Key Lab Yangtze River Water Environm MOE, State Key Lab Pollut Control & Resources Reuse, Shanghai 200092, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
3.Tongji Univ, Inst Modern Agr Sci & Engn, Natl Engn Res Ctr Facil Agr, Shanghai 200092, Peoples R China

Recommended Citation:
Zhang, Yalei,Shen, Zheng,Zhou, Xuefei,et al. Solvent isotope effect and mechanism for the production of hydrogen and lactic acid from glycerol under hydrothermal alkaline conditions[J]. GREEN CHEMISTRY,2012,14(12):3285-3288.
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