中国科学院大连化学物理研究所机构知识库
Advanced  
DICP OpenIR  > 中国科学院大连化学物理研究所  > 期刊论文
题名: Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols
作者: Xu, Weiliang2;  Zhou, Yonggui1;  Wang, Ruimin3;  Wu, Guotao1;  Chen, Ping1
刊名: ORGANIC & BIOMOLECULAR CHEMISTRY
发表日期: 2012
DOI: 10.1039/c1ob06368e
卷: 10, 期:2, 页:367-371
收录类别: SCI ;  IC ;  CCR
文章类型: Article
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Lithium amidoborane (LiNH2BH3, LiAB for short), is capable of chemoselectively reducing alpha,beta-unsaturated ketones to the corresponding allylic alcohols at ambient temperature. A mechanistic study shows that the reduction is via a double hydrogen transfer process. The protic H(N) and hydridic H(B) in amidoborane add to the O and C sites of the carbonyl group, respectively.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  AMMONIA-BORANE ;  SODIUM-BOROHYDRIDE ;  CARBONYL-COMPOUNDS ;  MECHANISTIC ASPECTS ;  METAL AMIDOBORANES ;  CONJUGATED KETONES ;  STORAGE MATERIAL ;  ALDEHYDES ;  RELEASE
语种: 英语
WOS记录号: WOS:000298555700025
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142873
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Dalian Inst Chem Phys, Dalian, Peoples R China
2.Natl Univ Singapore, Singapore 117548, Singapore
3.Inner Mongolia Univ, Hohhot, Peoples R China

Recommended Citation:
Xu, Weiliang,Zhou, Yonggui,Wang, Ruimin,et al. Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2012,10(2):367-371.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Xu, Weiliang]'s Articles
 [Zhou, Yonggui]'s Articles
 [Wang, Ruimin]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Xu, Weiliang]‘s Articles
 [Zhou, Yonggui]‘s Articles
 [Wang, Ruimin]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace