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Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols
Xu, Weiliang2; Zhou, Yonggui1; Wang, Ruimin3; Wu, Guotao1; Chen, Ping1
刊名ORGANIC & BIOMOLECULAR CHEMISTRY
2012
DOI10.1039/c1ob06368e
10期:2页:367-371
收录类别SCI ; IC ; CCR
文章类型Article
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC TRANSFER HYDROGENATION ; AMMONIA-BORANE ; SODIUM-BOROHYDRIDE ; CARBONYL-COMPOUNDS ; MECHANISTIC ASPECTS ; METAL AMIDOBORANES ; CONJUGATED KETONES ; STORAGE MATERIAL ; ALDEHYDES ; RELEASE
英文摘要Lithium amidoborane (LiNH2BH3, LiAB for short), is capable of chemoselectively reducing alpha,beta-unsaturated ketones to the corresponding allylic alcohols at ambient temperature. A mechanistic study shows that the reduction is via a double hydrogen transfer process. The protic H(N) and hydridic H(B) in amidoborane add to the O and C sites of the carbonyl group, respectively.
语种英语
WOS记录号WOS:000298555700025
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被引频次:9[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142873
专题中国科学院大连化学物理研究所
作者单位1.Dalian Inst Chem Phys, Dalian, Peoples R China
2.Natl Univ Singapore, Singapore 117548, Singapore
3.Inner Mongolia Univ, Hohhot, Peoples R China
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GB/T 7714
Xu, Weiliang,Zhou, Yonggui,Wang, Ruimin,et al. Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2012,10(2):367-371.
APA Xu, Weiliang,Zhou, Yonggui,Wang, Ruimin,Wu, Guotao,&Chen, Ping.(2012).Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols.ORGANIC & BIOMOLECULAR CHEMISTRY,10(2),367-371.
MLA Xu, Weiliang,et al."Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols".ORGANIC & BIOMOLECULAR CHEMISTRY 10.2(2012):367-371.
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