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Merging Organocatalysis with Transition Metal Catalysis: Highly Stereoselective alpha-Alkylation of Aldehydes
Xiao, Jian
刊名ORGANIC LETTERS
2012-04-06
DOI10.1021/ol3002859
14期:7页:1716-1719
收录类别SCI ; IC ; CCR
文章类型Article
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]CHIRAL FERROCENE LIGANDS ; ACID BINARY-SYSTEM ; ASYMMETRIC ALKYLATION ; COOPERATIVE CATALYSIS ; ENANTIOSELECTIVE SYNTHESIS ; RELAY CATALYSIS ; CYCLIC-KETONES ; ENE REACTION ; ALCOHOLS ; INDOLES
英文摘要The unprecedented cooperative systems involving a diarylprolinol silyl ether with various Lewis acids have been found to effect the highly enantioselective intermolecular alpha-alkylation of aldehydes. A wide variety of aldehydes and alcohols can be transformed into the desired highly functionalized aldehydes In high yields, excellent enantioselectivities, and good diastereoselectivities at room temperature under mild conditions.
语种英语
WOS记录号WOS:000302387800015
引用统计
被引频次:94[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142895
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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Xiao, Jian. Merging Organocatalysis with Transition Metal Catalysis: Highly Stereoselective alpha-Alkylation of Aldehydes[J]. ORGANIC LETTERS,2012,14(7):1716-1719.
APA Xiao, Jian.(2012).Merging Organocatalysis with Transition Metal Catalysis: Highly Stereoselective alpha-Alkylation of Aldehydes.ORGANIC LETTERS,14(7),1716-1719.
MLA Xiao, Jian."Merging Organocatalysis with Transition Metal Catalysis: Highly Stereoselective alpha-Alkylation of Aldehydes".ORGANIC LETTERS 14.7(2012):1716-1719.
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