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题名: Merging Organocatalysis with Transition Metal Catalysis: Highly Stereoselective alpha-Alkylation of Aldehydes
作者: Xiao, Jian
刊名: ORGANIC LETTERS
发表日期: 2012-04-06
DOI: 10.1021/ol3002859
卷: 14, 期:7, 页:1716-1719
收录类别: SCI ;  IC ;  CCR
文章类型: Article
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The unprecedented cooperative systems involving a diarylprolinol silyl ether with various Lewis acids have been found to effect the highly enantioselective intermolecular alpha-alkylation of aldehydes. A wide variety of aldehydes and alcohols can be transformed into the desired highly functionalized aldehydes In high yields, excellent enantioselectivities, and good diastereoselectivities at room temperature under mild conditions.
关键词[WOS]: CHIRAL FERROCENE LIGANDS ;  ACID BINARY-SYSTEM ;  ASYMMETRIC ALKYLATION ;  COOPERATIVE CATALYSIS ;  ENANTIOSELECTIVE SYNTHESIS ;  RELAY CATALYSIS ;  CYCLIC-KETONES ;  ENE REACTION ;  ALCOHOLS ;  INDOLES
语种: 英语
WOS记录号: WOS:000302387800015
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142895
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Xiao, Jian. Merging Organocatalysis with Transition Metal Catalysis: Highly Stereoselective alpha-Alkylation of Aldehydes[J]. ORGANIC LETTERS,2012,14(7):1716-1719.
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