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题名: Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions
作者: Wang, Lianyue1, 2, 3;  Li, Jun1, 2;  Yang, Hua1, 2, 3;  Lv, Ying1, 2;  Gao, Shuang1, 2
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2012-01-06
DOI: 10.1021/jo202301s
卷: 77, 期:1, 页:790-794
收录类别: SCI ;  CCR
文章类型: Article
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: We have developed a simple and practical process for the oxidation of alcohols to the corresponding carbonyl compounds by using a low catalytic amount of DDQ, NaNO2 as a cocatalyst, and molecular oxygen as terminal oxidant. Nitric oxide generated in situ by NaNO2 in the presence of AcOH is essential for the realization of the catalytic cycle at room temperature. The practical utility of this catalytic process has been demonstrated in the gram-scale oxidation of cinnamyl alcohol.
关键词[WOS]: EFFICIENT AEROBIC OXIDATION ;  TRANSITION-METAL-FREE ;  HIGHLY EFFICIENT ;  ACID-CHLORIDES ;  PALLADIUM NANOPARTICLES ;  PROPARGYLIC ALCOHOLS ;  OXIDASE CATALYSIS ;  BENZYLIC ALCOHOLS ;  CARBOXYLIC-ACIDS ;  ALDEHYDES
语种: 英语
WOS记录号: WOS:000298827600088
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142910
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, DNL, Dalian Natl Lab Clean Energy, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

Recommended Citation:
Wang, Lianyue,Li, Jun,Yang, Hua,et al. Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions[J]. JOURNAL OF ORGANIC CHEMISTRY,2012,77(1):790-794.
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