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Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions
Wang, Lianyue1,2,3; Li, Jun1,2; Yang, Hua1,2,3; Lv, Ying1,2; Gao, Shuang1,2
Source PublicationJOURNAL OF ORGANIC CHEMISTRY
2012-01-06
DOI10.1021/jo202301s
Volume77Issue:1Pages:790-794
Indexed BySCI ; CCR
SubtypeArticle
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordEFFICIENT AEROBIC OXIDATION ; TRANSITION-METAL-FREE ; HIGHLY EFFICIENT ; ACID-CHLORIDES ; PALLADIUM NANOPARTICLES ; PROPARGYLIC ALCOHOLS ; OXIDASE CATALYSIS ; BENZYLIC ALCOHOLS ; CARBOXYLIC-ACIDS ; ALDEHYDES
AbstractWe have developed a simple and practical process for the oxidation of alcohols to the corresponding carbonyl compounds by using a low catalytic amount of DDQ, NaNO2 as a cocatalyst, and molecular oxygen as terminal oxidant. Nitric oxide generated in situ by NaNO2 in the presence of AcOH is essential for the realization of the catalytic cycle at room temperature. The practical utility of this catalytic process has been demonstrated in the gram-scale oxidation of cinnamyl alcohol.
Language英语
WOS IDWOS:000298827600088
Citation statistics
Cited Times:49[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142910
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, DNL, Dalian Natl Lab Clean Energy, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Lianyue,Li, Jun,Yang, Hua,et al. Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions[J]. JOURNAL OF ORGANIC CHEMISTRY,2012,77(1):790-794.
APA Wang, Lianyue,Li, Jun,Yang, Hua,Lv, Ying,&Gao, Shuang.(2012).Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions.JOURNAL OF ORGANIC CHEMISTRY,77(1),790-794.
MLA Wang, Lianyue,et al."Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions".JOURNAL OF ORGANIC CHEMISTRY 77.1(2012):790-794.
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