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Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions
Wang, Lianyue1,2,3; Li, Jun1,2; Yang, Hua1,2,3; Lv, Ying1,2; Gao, Shuang1,2
刊名JOURNAL OF ORGANIC CHEMISTRY
2012-01-06
DOI10.1021/jo202301s
77期:1页:790-794
收录类别SCI ; CCR
文章类型Article
类目[WOS]Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]EFFICIENT AEROBIC OXIDATION ; TRANSITION-METAL-FREE ; HIGHLY EFFICIENT ; ACID-CHLORIDES ; PALLADIUM NANOPARTICLES ; PROPARGYLIC ALCOHOLS ; OXIDASE CATALYSIS ; BENZYLIC ALCOHOLS ; CARBOXYLIC-ACIDS ; ALDEHYDES
英文摘要We have developed a simple and practical process for the oxidation of alcohols to the corresponding carbonyl compounds by using a low catalytic amount of DDQ, NaNO2 as a cocatalyst, and molecular oxygen as terminal oxidant. Nitric oxide generated in situ by NaNO2 in the presence of AcOH is essential for the realization of the catalytic cycle at room temperature. The practical utility of this catalytic process has been demonstrated in the gram-scale oxidation of cinnamyl alcohol.
语种英语
WOS记录号WOS:000298827600088
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/142910
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, DNL, Dalian Natl Lab Clean Energy, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
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GB/T 7714
Wang, Lianyue,Li, Jun,Yang, Hua,et al. Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions[J]. JOURNAL OF ORGANIC CHEMISTRY,2012,77(1):790-794.
APA Wang, Lianyue,Li, Jun,Yang, Hua,Lv, Ying,&Gao, Shuang.(2012).Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions.JOURNAL OF ORGANIC CHEMISTRY,77(1),790-794.
MLA Wang, Lianyue,et al."Selective Oxidation of Unsaturated Alcohols Catalyzed by Sodium Nitrite and 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone with Molecular Oxygen under Mild Conditions".JOURNAL OF ORGANIC CHEMISTRY 77.1(2012):790-794.
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