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Density, Electrical Conductivity, and Dynamic Viscosity of N-Alkyl-4-methylpyridinium Bis(trifluoromethylsulfonyl)imide
Liu, Qing-Shan1,2,3; Li, Pei-Pei3; Welz-Biermann, Urs3; Liu, Xiao-Xia1; Chen, Jian2
Source PublicationJOURNAL OF CHEMICAL AND ENGINEERING DATA
2012-11-01
DOI10.1021/je3004645
Volume57Issue:11Pages:2999-3004
Indexed BySCI
SubtypeArticle
WOS SubjectChemistry, Multidisciplinary ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordPROTIC IONIC LIQUIDS ; PHYSICOCHEMICAL PROPERTIES ; THERMODYNAMIC PROPERTIES ; PHASE-TRANSITION ; SURFACE-TENSION ; PURE ; N=2
AbstractTwo air and water stable hydrophobic ionic liquids N-alkyl-4-methylpyridinium bis(trifluoromethylsulfonyl)imide ([C(n)4mpy][NTf2], n = 2, 4) were synthesized and characterized. The density, electrical conductivity, and dynamic viscosity were measured and estimated in the range of T = (278.15 to 363.15) K. The melting temperature, glass transition temperature, and decomposition temperature of the two ILs were determined according to the differential scanning calorimetry (DSC) and thermogravimetric analyzer (TG). The molecular volume, standard molar entropy, and lattice energy were estimated in terms of empirical equations on the basis of the density values. The electric:I conductivity and dynamic viscosity values dependence on temperature were fitted by the Vogel-Fulcher-Tamman equation. The molar conductivity was calculated by the density and electrical conductivity.
Language英语
WOS IDWOS:000310768900014
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Cited Times:19[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142928
Collection中国科学院大连化学物理研究所
Affiliation1.Northeastern Univ, Dept Chem, Shenyang 110819, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Adv Rechargeable Batteries, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Liu, Qing-Shan,Li, Pei-Pei,Welz-Biermann, Urs,et al. Density, Electrical Conductivity, and Dynamic Viscosity of N-Alkyl-4-methylpyridinium Bis(trifluoromethylsulfonyl)imide[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2012,57(11):2999-3004.
APA Liu, Qing-Shan,Li, Pei-Pei,Welz-Biermann, Urs,Liu, Xiao-Xia,&Chen, Jian.(2012).Density, Electrical Conductivity, and Dynamic Viscosity of N-Alkyl-4-methylpyridinium Bis(trifluoromethylsulfonyl)imide.JOURNAL OF CHEMICAL AND ENGINEERING DATA,57(11),2999-3004.
MLA Liu, Qing-Shan,et al."Density, Electrical Conductivity, and Dynamic Viscosity of N-Alkyl-4-methylpyridinium Bis(trifluoromethylsulfonyl)imide".JOURNAL OF CHEMICAL AND ENGINEERING DATA 57.11(2012):2999-3004.
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