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题名: Asymmetric Organocatalytic Cascade Michael/Michael/Henry Reaction Sequence: Control of All Stereocenters in One Cyclohexane Skeleton
作者: Mao, Zhifeng1, 2, 3;  Jia, Yaomei1, 2;  Xu, Zhaoqing3;  Wang, Rui1, 2
关键词: asymmetric catalysis ;  cyclohexanes ;  domino reactions ;  Henry reaction ;  Michael addition
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2012-05-01
DOI: 10.1002/adsc.201200008
卷: 354, 期:8, 页:1401-1406
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The highly diastereo- and enantioselective relay cascade Michael/Michael/Henry reaction catalyzed by combination of readily available diphenylprolinol silyl ether and the quinine thiourea in a one-pot fashion has been developed. Up to 70% yield and up to >99% enantioselectivity of the single major isomer were obtained from the cascade reactions.
关键词[WOS]: DIPHENYLPROLINOL SILYL ETHER ;  MICHAEL-HENRY REACTIONS ;  HIGH-YIELDING SYNTHESIS ;  FUNCTIONALIZED CYCLOHEXANES ;  INHIBITOR (-)-OSELTAMIVIR ;  CONTIGUOUS STEREOCENTERS ;  BIFUNCTIONAL THIOUREA ;  TANDEM REACTIONS ;  BOND DONORS ;  CATALYSIS
语种: 英语
WOS记录号: WOS:000304345100003
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/142942
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Lanzhou Univ, Sch Basic Med Sci, Key Lab Preclin Study New Drugs Gansu Prov, Inst Biochem & Mol Biol,Sch Life Sci, Lanzhou 730000, Peoples R China
2.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

Recommended Citation:
Mao, Zhifeng,Jia, Yaomei,Xu, Zhaoqing,et al. Asymmetric Organocatalytic Cascade Michael/Michael/Henry Reaction Sequence: Control of All Stereocenters in One Cyclohexane Skeleton[J]. ADVANCED SYNTHESIS & CATALYSIS,2012,354(8):1401-1406.
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