Synthesis, optical properties and ultrafast dynamics of a 2,1,3-benzothiadiazole-based red emitter with intense fluorescence and large two-photon absorption cross-section

doi:10.1016/j.dyepig.2011.06.032

DICP OpenIR

	Synthesis, optical properties and ultrafast dynamics of a 2,1,3-benzothiadiazole-based red emitter with intense fluorescence and large two-photon absorption cross-section
	Wang, Yaochuan 1,2; Huang, Ju 3,4; Zhou, Hui 1; Ma, Guohong 5; Qian, Shixiong 1; Zhu, Xu-hui 3,4
关键词	Two-photon Absorption Two-photon Fluorescence Excited State Dynamics Intramolecular Charge Transfer Benzothiadiazole Red Emitter
刊名	DYES AND PIGMENTS
	2012
DOI	10.1016/j.dyepig.2011.06.032
卷	92 期:1 页:573-579
收录类别	SCI
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences ; Technology
类目[WOS]	Chemistry, Applied ; Engineering, Chemical ; Materials Science, Textiles
研究领域[WOS]	Chemistry ; Engineering ; Materials Science
关键词[WOS]	ABSORBING MATERIALS ; DITHIENYLBENZOTHIADIAZOLE ; EFFICIENT ; DYES ; ELECTROLUMINESCENCE ; MOLECULES ; DESIGN ; DIODES ; DONOR
英文摘要	A new 2,1,3-benzothiadiazole-based red fluorescent compound with a D-A-D type structure was synthesized and characterized. The central 2,1,3-benzothiadiazole core was symmetrically connected via the 4,7-positions with two donor groups in which the 7-position of a fluorenyl ring was substituted with a carbazol-9-yl moiety and the 2-position was substituted by a 5-thienyl moiety. The carbazol moieties were further derivatized by two 2-naphthyl moieties at the 3,6-positions. Femtosecond laser spectroscopic techniques including excited state fluorescence and pump-probe technique investigations, together with steady state absorption and one-photon fluorescence spectra, were employed to systematically investigate the optical properties and ultrafast dynamics of the new compound in tetrahydrofuran solution. It shows a large two-photon absorption cross-section and high fluorescence quantum yield, indicating potential application in two-photon fluorescence imaging field. The ultrafast dynamics results reveal competition between a pure excited state relaxation process and stimulated radiation in the red wavelength region. (C) 2011 Published by Elsevier Ltd.
语种	英语
WOS记录号	WOS:000295952300010
引用统计
文献类型	期刊论文
条目标识符	http://cas-ir.dicp.ac.cn/handle/321008/142957
专题	中国科学院大连化学物理研究所
作者单位	1.Fudan Univ, Dept Phys, Surface Phys Lab, State Key Lab, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.S China Univ Technol, State Key Lab Phys & Chem Luminescence, Guangzhou 510640, Peoples R China 4.S China Univ Technol, Inst Polymer Optoelect Mat & Devices, Guangzhou 510640, Peoples R China 5.Shanghai Univ, Dept Phys, Shanghai 200000, Peoples R China
推荐引用方式 GB/T 7714	Wang, Yaochuan,Huang, Ju,Zhou, Hui,et al. Synthesis, optical properties and ultrafast dynamics of a 2,1,3-benzothiadiazole-based red emitter with intense fluorescence and large two-photon absorption cross-section[J]. DYES AND PIGMENTS,2012,92(1):573-579.
APA	Wang, Yaochuan,Huang, Ju,Zhou, Hui,Ma, Guohong,Qian, Shixiong,&Zhu, Xu-hui.(2012).Synthesis, optical properties and ultrafast dynamics of a 2,1,3-benzothiadiazole-based red emitter with intense fluorescence and large two-photon absorption cross-section.DYES AND PIGMENTS,92(1),573-579.
MLA	Wang, Yaochuan,et al."Synthesis, optical properties and ultrafast dynamics of a 2,1,3-benzothiadiazole-based red emitter with intense fluorescence and large two-photon absorption cross-section".DYES AND PIGMENTS 92.1(2012):573-579.