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Localized Emitting State and Energy Transfer Properties of Quadrupolar Chromophores and (Multi)Branched Derivatives
Yan, Linyin1,2; Chen, Xudong1,2; He, Qingguo1,2; Wang, Yingying1,2; Wang, Xuefei1,2; Guo, Qianjin1,2; Bai, Fenglian1,2; Xia, Andong1,2; Aumiler, Damir1,3; Vdovic, Silvije1,3; Lin, ShengHien4
Source PublicationJOURNAL OF PHYSICAL CHEMISTRY A
2012-08-30
DOI10.1021/jp305407s
Volume116Issue:34Pages:8693-8705
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS Research AreaChemistry ; Physics
WOS Keyword2-PHOTON ABSORPTION PROPERTIES ; EXCITATION CROSS-SECTIONS ; POLYMERS INCORPORATING 2,2'-BIPYRIDINES ; INTRAMOLECULAR CHARGE-TRANSFER ; NONLINEAR-OPTICAL PROPERTIES ; PHOTOPHYSICAL PROPERTIES ; MULTIPHOTON ABSORPTION ; TRIPHENYLBENZENE DERIVATIVES ; MULTIBRANCHED STRUCTURES ; ORGANIC CHROMOPHORES
AbstractIn order to better understand the nature of intramolecular charge and energy transfer in multibranched molecules, we have synthesized and studied the photophysical properties of a monomer quadrupolar chromophore with donor-acceptor-donor (D-A-D) electronic push-pull structure, together with its V-shaped dimer and star-shaped trimers. The comparison of steady-state absorption spectra and fluorescence excitation anisotropy spectra of these chromophores show evidence of weak interaction (such as charge and energy transfer) among the branches. Moreover, similar fluorescence and solvation behavior of monomer and branched chromophores (dimer and trimer) implies that the interaction among the branches is not strong enough to make a significant distinction between these molecules, due to the weak interaction and intrinsic structural disorder in branched molecules. Furthermore, the interaction between the branches can be enhanced by inserting pi bridge spacers (-C=C- or -C C-) between the core donor and the acceptor. This improvement leads to a remarkable enhancement of two photon cross sections, indicating that the interbranch interaction results in the amplification of transition dipole moments between ground states and excited states. The interpretations of the observed photophysical properties are further supported by theoretical investigation, which reveal that the changes of the transition dipole moments of the branched quadrupolar chromophores play a critical role in observed the two-photon absorption (2PA) cross-section for an intramolecular charge transfer (ICT) state interaction in the multibranched quadrupolar chromophores.
Language英语
WOS IDWOS:000308119800005
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/142985
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci BNLMS, Beijing 100190, Peoples R China
3.Inst Phys, Zagreb 10000, Croatia
4.Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 30010, Taiwan
Recommended Citation
GB/T 7714
Yan, Linyin,Chen, Xudong,He, Qingguo,et al. Localized Emitting State and Energy Transfer Properties of Quadrupolar Chromophores and (Multi)Branched Derivatives[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2012,116(34):8693-8705.
APA Yan, Linyin.,Chen, Xudong.,He, Qingguo.,Wang, Yingying.,Wang, Xuefei.,...&Lin, ShengHien.(2012).Localized Emitting State and Energy Transfer Properties of Quadrupolar Chromophores and (Multi)Branched Derivatives.JOURNAL OF PHYSICAL CHEMISTRY A,116(34),8693-8705.
MLA Yan, Linyin,et al."Localized Emitting State and Energy Transfer Properties of Quadrupolar Chromophores and (Multi)Branched Derivatives".JOURNAL OF PHYSICAL CHEMISTRY A 116.34(2012):8693-8705.
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