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Mesoporous WO3 Supported Pt Catalyst for Hydrogenolysis of Glycerol to 1,3-Propanediol
Liu Longjie1,2; Zhang Yanhua1; Wang Aiqin1; Zhang Tao1
关键词Mesoporous Tungsten Trioxide Platinum Glycerol Hydrogenolysis 1 3-propanediol
刊名CHINESE JOURNAL OF CATALYSIS
2012-08-01
DOI10.1016/S1872-2067(11)60425-7
33期:8页:1257-1261
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]SPECTROSCOPY ; PT/WO3/ZRO2
英文摘要Mesoporous tungsten trioxide (m-WO3) was prepared using an evaporation-induced self-assembly method and was used as the support of Pt for hydrogenolysis of glycerol to produce 1,3-propanediol. In comparison with commercial WO3, the m-WO3 presents a much larger surface area and better reducibility, which make the Pt particles highly dispersed on the support. At a reaction condition of 180 degrees C, 5.5 MPa H-2, and reaction time of 12 h, the Pt/m-WO3 catalyst afforded 18.0% conversion of glycerol and 39.2% selectivity for 1,3-propanediol, both of which are much higher than those on commercial Pt/WO3 catalyst.
语种英语
WOS记录号WOS:000307624400002
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143002
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Liu Longjie,Zhang Yanhua,Wang Aiqin,et al. Mesoporous WO3 Supported Pt Catalyst for Hydrogenolysis of Glycerol to 1,3-Propanediol[J]. CHINESE JOURNAL OF CATALYSIS,2012,33(8):1257-1261.
APA Liu Longjie,Zhang Yanhua,Wang Aiqin,&Zhang Tao.(2012).Mesoporous WO3 Supported Pt Catalyst for Hydrogenolysis of Glycerol to 1,3-Propanediol.CHINESE JOURNAL OF CATALYSIS,33(8),1257-1261.
MLA Liu Longjie,et al."Mesoporous WO3 Supported Pt Catalyst for Hydrogenolysis of Glycerol to 1,3-Propanediol".CHINESE JOURNAL OF CATALYSIS 33.8(2012):1257-1261.
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