DICP OpenIR
Catalytic selective etherification of hydroxyl groups in 5-hydroxymethylfurfural over H4SiW12O40/MCM-41 nanospheres for liquid fuel production
Che, Penghua1,2; Lu, Fang1; Zhang, Junjie1,2; Huang, Yizheng1; Nie, Xin1; Gao, Jin1; Xu, Jie1
关键词Etherification 5-hydroxymethylfurfural Tungstosilicic Acid Mcm-41 Nanospheres 5-ethoxymethylfurfural
刊名BIORESOURCE TECHNOLOGY
2012-09-01
DOI10.1016/j.biortech.2012.06.001
119页:433-436
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Technology
类目[WOS]Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
研究领域[WOS]Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
关键词[WOS]CONVERSION ; BIOMASS ; EFFICIENT
英文摘要5-Hydroxymethylfurfural (HMF) is an important biomass-derived building block, but production and sustainable utilization of HMF remain challenging due to reactions of the highly reactive functional groups of this compound. H4SiW12O40/MCM-41 nanospheres were developed that exhibit 84.1% selectivity to 5-ethoxymethylfurfural (EMF) when HMF conversion reaches 92.0%, during etherification of 5-hydroxymethylfurfural (HMF) with ethanol under mild conditions. The catalyst could be reused, and its activity remained unaffected over five cycles. The strong acidity of the catalyst significantly enhanced etherification. The acetalized byproducts, 5-(diethoxymethyl)-2-furanmethanol and the HMF-dimer (5,5'(oxybis(methylene))bis-2-furfural), can be converted into HMF and then transformed to the main product, EMF, by using this catalyst to shift the reaction equilibrium. (C) 2012 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000307617600056
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143025
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Che, Penghua,Lu, Fang,Zhang, Junjie,et al. Catalytic selective etherification of hydroxyl groups in 5-hydroxymethylfurfural over H4SiW12O40/MCM-41 nanospheres for liquid fuel production[J]. BIORESOURCE TECHNOLOGY,2012,119:433-436.
APA Che, Penghua.,Lu, Fang.,Zhang, Junjie.,Huang, Yizheng.,Nie, Xin.,...&Xu, Jie.(2012).Catalytic selective etherification of hydroxyl groups in 5-hydroxymethylfurfural over H4SiW12O40/MCM-41 nanospheres for liquid fuel production.BIORESOURCE TECHNOLOGY,119,433-436.
MLA Che, Penghua,et al."Catalytic selective etherification of hydroxyl groups in 5-hydroxymethylfurfural over H4SiW12O40/MCM-41 nanospheres for liquid fuel production".BIORESOURCE TECHNOLOGY 119(2012):433-436.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Che, Penghua]的文章
[Lu, Fang]的文章
[Zhang, Junjie]的文章
百度学术
百度学术中相似的文章
[Che, Penghua]的文章
[Lu, Fang]的文章
[Zhang, Junjie]的文章
必应学术
必应学术中相似的文章
[Che, Penghua]的文章
[Lu, Fang]的文章
[Zhang, Junjie]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。