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Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells
Wang, Shuang1,3; Sun, Li-Xian1,4; Xu, Fen2; Jiao, Cheng-Li1,3; Zhang, Jian1; Zhou, Huai-Ying4; Huang, Feng-Lei5
KeywordHydrogen Generation Mg-based-material Ball Milling Hydrolysis Reaction Kinetics
Source PublicationINTERNATIONAL JOURNAL OF HYDROGEN ENERGY
2012-04-01
DOI10.1016/j.ijhydene.2012.01.099
Volume37Issue:8Pages:6771-6775
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Physical ; Electrochemistry ; Energy & Fuels
WOS Research AreaChemistry ; Electrochemistry ; Energy & Fuels
WOS KeywordCHEMICAL HYDRIDES ; MAGNESIUM ; WATER
AbstractIn this paper, the hydrolysis properties for hydrogen generation by Mg-metal chlorides composites in pure water are investigated. The composites were prepared by high energy ball milling. It is found that the Mg-metal chlorides composites are very promising for hydrogen generation by hydrolysis reaction. The micro-galvanic cell formed by Mg and the other metal which produced by replacement reaction occurred during the ball-milling process is very effective for improving the hydrolysis reactivity. Based on the investigations of different kinds of chlorides additives, it is found that the Mg-10 wt% FeCl3 composite ball-milled for 30 min has the best hydrolysis properties with an initial hydrogen generation rate of 1479.1 ml*g(-1) min(-1) and a theoretical hydrogen production yield of 98% in 2 min. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Language英语
WOS IDWOS:000303952300047
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/143026
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China
2.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
4.Guilin Univ Elect Technol, Dept Mat Sci & Engn, Guilin 541004, Peoples R China
5.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China
Recommended Citation
GB/T 7714
Wang, Shuang,Sun, Li-Xian,Xu, Fen,et al. Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2012,37(8):6771-6775.
APA Wang, Shuang.,Sun, Li-Xian.,Xu, Fen.,Jiao, Cheng-Li.,Zhang, Jian.,...&Huang, Feng-Lei.(2012).Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,37(8),6771-6775.
MLA Wang, Shuang,et al."Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 37.8(2012):6771-6775.
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