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题名: FeCl3 center dot 6H(2)O-Catalyzed Alkenylation of Indoles with Aldehydes
作者: Yang, Qin1;  Wang, Liandi1;  Guo, Tenglong1;  Yu, Zhengkun1, 2
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2012-09-21
DOI: 10.1021/jo301416s
卷: 77, 期:18, 页:8355-8361
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: FeCl3 center dot 6H(2)O-catalyzed efficient C3-alkenylation of indoles was realized through the condensation of aldehydes and indole derivatives in the presence of 2 equiv of ethanol at ambient temperature, forming 3-vinylindoles in up to 93% yields. Ethanol promoted formation of the desired products. An obvious solvent effect was observed, and bisindoles were identified as the reaction intermediates.
关键词[WOS]: FRIEDEL-CRAFTS ALKYLATION ;  C-H FUNCTIONALIZATION ;  1,3-DICARBONYL COMPOUNDS ;  CATALYZED REACTIONS ;  COUPLING REACTIONS ;  EFFICIENT ;  PYRROLES ;  C2-ALKENYLATION ;  DERIVATIVES ;  CYCLIZATION
语种: 英语
WOS记录号: WOS:000308957700060
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/143058
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Yang, Qin,Wang, Liandi,Guo, Tenglong,et al. FeCl3 center dot 6H(2)O-Catalyzed Alkenylation of Indoles with Aldehydes[J]. JOURNAL OF ORGANIC CHEMISTRY,2012,77(18):8355-8361.
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