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题名: Iridium-Catalyzed Asymmetric Hydrogenation of 3-Substituted 2H-1,4-Benzoxazines
作者: Gao, Kai1;  Yu, Chang-Bin1;  Wang, Duo-Sheng1;  Zhou, Yong-Gui1, 2
关键词: asymmetric hydrogenation ;  benzoxazines ;  chiral amines ;  cyclic imines ;  iridium
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2012-02-01
DOI: 10.1002/adsc.201100568
卷: 354, 期:2-3, 页:483-488
收录类别: SCI ;  IC
文章类型: Review
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Applied ;  Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: The highly enantioselective hydrogenation of 3-aryl-2H-1,4-benzoxazines was achieved using the (cyclooctadiene)iridium chloride dimer/(S)-SegPhos/iodine {[Ir(COD)Cl]2/(S)-SegPhos/I2} system as catalyst with up to 92% ee. The 3-styryl-2H-1,4-benzoxazine derivatives were also hydrogenated by the iridium catalyst and Pd/C in two consecutive steps whereby 9395% ee values were obtained.
关键词[WOS]: HIGHLY ENANTIOSELECTIVE HYDROGENATION ;  N-ARYL IMINES ;  KINETIC RESOLUTION ;  HETEROAROMATIC-COMPOUNDS ;  REDUCTIVE AMINATION ;  KEY INTERMEDIATE ;  ACYCLIC IMINES ;  CYCLIC IMINES ;  COMPLEXES ;  QUINOLINES
语种: 英语
WOS记录号: WOS:000300448400029
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/143097
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Gao, Kai,Yu, Chang-Bin,Wang, Duo-Sheng,et al. Iridium-Catalyzed Asymmetric Hydrogenation of 3-Substituted 2H-1,4-Benzoxazines[J]. ADVANCED SYNTHESIS & CATALYSIS,2012,354(2-3):483-488.
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