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A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl-Pyrazole Complex Catalyst for Transfer Hydrogenation of Ketones
Jin, Weiwei1; Wang, Liandi1; Yu, Zhengkun1,2
刊名ORGANOMETALLICS
2012-08-13
DOI10.1021/om300602w
31期:15页:5664-5667
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]ASYMMETRIC TRANSFER HYDROGENATION ; LIGAND BIFUNCTIONAL CATALYSIS ; CARBONYL-COMPOUNDS ; PLATINUM COMPLEXES ; IMIDAZOLYL LIGAND ; H-2 HYDROGENATION ; PINCER COMPLEXES ; BEARING ; ALCOHOLS ; REDUCTION
英文摘要Ruthenium(II) complexes bearing a pyrazolyl-pyridyl-pyrazole ligand were synthesized and exhibited exceptionally high catalytic activity in the transfer hydrogenation of ketones in refluxing isopropyl alcohol, reaching final TOFs up to 720 000 h(-1). The beta-NH functionality of the pyrazole arm in the ligand demonstrated a remarkable acceleration effect on the reaction rate. The unsymmetrical nature (hemilability) and presence of the convertible NH group of the ligand is attributed to the high catalytic activity of the complex catalyst.
语种英语
WOS记录号WOS:000307422200052
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143126
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
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GB/T 7714
Jin, Weiwei,Wang, Liandi,Yu, Zhengkun. A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl-Pyrazole Complex Catalyst for Transfer Hydrogenation of Ketones[J]. ORGANOMETALLICS,2012,31(15):5664-5667.
APA Jin, Weiwei,Wang, Liandi,&Yu, Zhengkun.(2012).A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl-Pyrazole Complex Catalyst for Transfer Hydrogenation of Ketones.ORGANOMETALLICS,31(15),5664-5667.
MLA Jin, Weiwei,et al."A Highly Active Ruthenium(II) Pyrazolyl-Pyridyl-Pyrazole Complex Catalyst for Transfer Hydrogenation of Ketones".ORGANOMETALLICS 31.15(2012):5664-5667.
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