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Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts
Song Xiangen1,3; Ding Yunjie1,2; Chen Weimiao1; Dong Wenda1,3; Pei Yanpeng1,3; Zang Juan1,3; Yan Li1; Lu Yuan1
关键词Carbon Monoxide Hydrogenation Oxygenates Metal Phosphides Silica Iron Phosphide Nickel Phosphide
刊名CHINESE JOURNAL OF CATALYSIS
2012-12-01
DOI10.1016/S1872-2067(11)60460-9
33期:12页:1938-1944
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
研究领域[WOS]Chemistry ; Engineering
关键词[WOS]SYNTHESIS GAS CONVERSION ; HIGH-TEMPERATURE ; RH CATALYSTS ; SYNGAS ; ETHANOL ; HYDRODESULFURIZATION ; AMMOXIDATION ; REDUCTION ; NI2P/SIO2
英文摘要A series of silica supported iron and nickel metal phosphides with different molar ratios of P to metal were synthesized by the temperature programmed reduction method. Their catalytic performance for CO hydrogenation in a fixed bed reactor was tested with the conditions of 553 K, 5.0 MPa, and H-2:CO = 2 (molar ratio). With the FePx/SiO2 catalysts (x denotes the molar ratio of P to metal), the product was a mixture of oxygenates containing methanol as the major component. With the NiPx/SiO2 samples, the liquid product was mainly methanol. The Fe2P, Fe3P, Ni, Ni2P, Ni3P, and Ni12P5 phases were stable during CO hydrogenation, while most of the metallic Fe phase transformed into iron carbide.
语种英语
WOS记录号WOS:000313139200010
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文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143133
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Song Xiangen,Ding Yunjie,Chen Weimiao,et al. Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2012,33(12):1938-1944.
APA Song Xiangen.,Ding Yunjie.,Chen Weimiao.,Dong Wenda.,Pei Yanpeng.,...&Lu Yuan.(2012).Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts.CHINESE JOURNAL OF CATALYSIS,33(12),1938-1944.
MLA Song Xiangen,et al."Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts".CHINESE JOURNAL OF CATALYSIS 33.12(2012):1938-1944.
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