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Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts
Song Xiangen1,3; Ding Yunjie1,2; Chen Weimiao1; Dong Wenda1,3; Pei Yanpeng1,3; Zang Juan1,3; Yan Li1; Lu Yuan1
KeywordCarbon Monoxide Hydrogenation Oxygenates Metal Phosphides Silica Iron Phosphide Nickel Phosphide
Source PublicationCHINESE JOURNAL OF CATALYSIS
2012-12-01
DOI10.1016/S1872-2067(11)60460-9
Volume33Issue:12Pages:1938-1944
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Engineering, Chemical
WOS Research AreaChemistry ; Engineering
WOS KeywordSYNTHESIS GAS CONVERSION ; HIGH-TEMPERATURE ; RH CATALYSTS ; SYNGAS ; ETHANOL ; HYDRODESULFURIZATION ; AMMOXIDATION ; REDUCTION ; NI2P/SIO2
AbstractA series of silica supported iron and nickel metal phosphides with different molar ratios of P to metal were synthesized by the temperature programmed reduction method. Their catalytic performance for CO hydrogenation in a fixed bed reactor was tested with the conditions of 553 K, 5.0 MPa, and H-2:CO = 2 (molar ratio). With the FePx/SiO2 catalysts (x denotes the molar ratio of P to metal), the product was a mixture of oxygenates containing methanol as the major component. With the NiPx/SiO2 samples, the liquid product was mainly methanol. The Fe2P, Fe3P, Ni, Ni2P, Ni3P, and Ni12P5 phases were stable during CO hydrogenation, while most of the metallic Fe phase transformed into iron carbide.
Language英语
WOS IDWOS:000313139200010
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/143133
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Song Xiangen,Ding Yunjie,Chen Weimiao,et al. Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts[J]. CHINESE JOURNAL OF CATALYSIS,2012,33(12):1938-1944.
APA Song Xiangen.,Ding Yunjie.,Chen Weimiao.,Dong Wenda.,Pei Yanpeng.,...&Lu Yuan.(2012).Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts.CHINESE JOURNAL OF CATALYSIS,33(12),1938-1944.
MLA Song Xiangen,et al."Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts".CHINESE JOURNAL OF CATALYSIS 33.12(2012):1938-1944.
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