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题名: Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen
作者: Wang, Lianyue1, 2, 3;  Li, Jun1, 3;  Lv, Ying1, 3;  Zhao, Gongda1, 3;  Gao, Shuang1, 3
关键词: palladium ;  oxidation ;  furans ;  alkynes ;  molecular oxygen
刊名: SYNLETT
发表日期: 2012-04-01
DOI: 10.1055/s-0031-1290526
期: 7, 页:1074-1078
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: A new approach to the synthesis of tetrasubstituted furans using aromatic alkynes catalyzed by PdCl2 in DMA (N,N-dimethylacetamide)-H2O with dioxygen as the sole oxidant is described, in which the oxygen atom of the furan was from water. The preliminary mechanistic understanding of this transformation was investigated.
关键词[WOS]: EFFICIENT SYNTHESIS ;  POLYSUBSTITUTED FURANS ;  SUBSTITUTED FURANS ;  MILD CONDITIONS ;  CYCLOISOMERIZATION ;  TRANSFORMATION ;  HETEROCYCLES ;  KETONES ;  ALKYNES ;  (Z)-2-EN-4-YN-1-OLS
语种: 英语
WOS记录号: WOS:000302858500018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/143141
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.DNL, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Wang, Lianyue,Li, Jun,Lv, Ying,et al. Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen[J]. SYNLETT,2012(7):1074-1078.
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