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Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen
Wang, Lianyue1,2,3; Li, Jun1,3; Lv, Ying1,3; Zhao, Gongda1,3; Gao, Shuang1,3
KeywordPalladium Oxidation Furans Alkynes Molecular Oxygen
Source PublicationSYNLETT
2012-04-01
DOI10.1055/s-0031-1290526
Issue7Pages:1074-1078
Indexed BySCI ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Organic
WOS Research AreaChemistry
WOS KeywordEFFICIENT SYNTHESIS ; POLYSUBSTITUTED FURANS ; SUBSTITUTED FURANS ; MILD CONDITIONS ; CYCLOISOMERIZATION ; TRANSFORMATION ; HETEROCYCLES ; KETONES ; ALKYNES ; (Z)-2-EN-4-YN-1-OLS
AbstractA new approach to the synthesis of tetrasubstituted furans using aromatic alkynes catalyzed by PdCl2 in DMA (N,N-dimethylacetamide)-H2O with dioxygen as the sole oxidant is described, in which the oxygen atom of the furan was from water. The preliminary mechanistic understanding of this transformation was investigated.
Language英语
WOS IDWOS:000302858500018
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/143141
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.DNL, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
Recommended Citation
GB/T 7714
Wang, Lianyue,Li, Jun,Lv, Ying,et al. Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen[J]. SYNLETT,2012(7):1074-1078.
APA Wang, Lianyue,Li, Jun,Lv, Ying,Zhao, Gongda,&Gao, Shuang.(2012).Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen.SYNLETT(7),1074-1078.
MLA Wang, Lianyue,et al."Unexpected Base-Promoted Synthesis of Tetrasubstituted Furans via Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bond with Molecular Oxygen".SYNLETT .7(2012):1074-1078.
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