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The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols
Xiao, Jian1,2; Zhao, Kai1; Loh, Teck-Peng1
刊名CHEMICAL COMMUNICATIONS
2012
DOI10.1039/c2cc30261f
48期:29页:3548-3550
收录类别SCI ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]CHIRAL FERROCENE LIGANDS ; ORGANIC-REACTIONS ; HOMOGENEOUS CATALYSIS ; BOND FORMATIONS ; AQUEOUS-MEDIA ; WATER ; ORGANOCATALYSIS ; INDOLES ; SOLVENT ; PATHWAY
英文摘要The acid free asymmetric intermolecular alpha-alkylation of aldehydes with alcohols has been discovered using trifluoroethanol as solvent. This unprecedented system affords the enantioenriched functionalized primary alcohols (after NaBH4 reduction) in high yields and good to excellent enantioselectivities with wide substrate scope in the absence of any acid additive.
语种英语
WOS记录号WOS:000301354400024
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143162
专题中国科学院大连化学物理研究所
作者单位1.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
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GB/T 7714
Xiao, Jian,Zhao, Kai,Loh, Teck-Peng. The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols[J]. CHEMICAL COMMUNICATIONS,2012,48(29):3548-3550.
APA Xiao, Jian,Zhao, Kai,&Loh, Teck-Peng.(2012).The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols.CHEMICAL COMMUNICATIONS,48(29),3548-3550.
MLA Xiao, Jian,et al."The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols".CHEMICAL COMMUNICATIONS 48.29(2012):3548-3550.
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