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Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins
Zhang, Tao1,2; Qi, Zisong1; Zhang, Xueyun1; Wu, Lamei2; Li, Xingwei1
KeywordCh Activation Cyclization Hydroacylation Olefins Rhodium
Source PublicationCHEMISTRY-A EUROPEAN JOURNAL
2014-03-17
DOI10.1002/chem.201400022
Volume20Issue:12Pages:3283-3287
Indexed BySCI ; IC ; CCR
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordC-H BOND ; INTERMOLECULAR HYDROACYLATION ; OXIDATIVE OLEFINATION ; DIRECTING GROUP ; RHODIUM ; ACTIVATION ; CLEAVAGE ; ALKYNES ; SALICYLALDEHYDES ; ALDEHYDES
AbstractMetal-catalyzed hydroacylation of olefins represents an important atom-economic synthetic process in CH activation. For the first time highly efficient (RhCp)-Cp-III*-catalyzed hydroacylation was realized in the coupling of N-sulfonyl 2-aminobenzaldehydes with both conjugated and aliphatic olefins, leading to the synthesis of various aryl ketones. Occasionally, oxidative coupling occurred when a silver(I) oxidant was used.
Language英语
WOS IDWOS:000332747400005
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/143172
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.South Cent Univ Nationalities, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Tao,Qi, Zisong,Zhang, Xueyun,et al. Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(12):3283-3287.
APA Zhang, Tao,Qi, Zisong,Zhang, Xueyun,Wu, Lamei,&Li, Xingwei.(2014).Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins.CHEMISTRY-A EUROPEAN JOURNAL,20(12),3283-3287.
MLA Zhang, Tao,et al."Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins".CHEMISTRY-A EUROPEAN JOURNAL 20.12(2014):3283-3287.
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