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Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins
Zhang, Tao1,2; Qi, Zisong1; Zhang, Xueyun1; Wu, Lamei2; Li, Xingwei1
关键词Ch Activation Cyclization Hydroacylation Olefins Rhodium
刊名CHEMISTRY-A EUROPEAN JOURNAL
2014-03-17
DOI10.1002/chem.201400022
20期:12页:3283-3287
收录类别SCI ; IC ; CCR
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Multidisciplinary
研究领域[WOS]Chemistry
关键词[WOS]C-H BOND ; INTERMOLECULAR HYDROACYLATION ; OXIDATIVE OLEFINATION ; DIRECTING GROUP ; RHODIUM ; ACTIVATION ; CLEAVAGE ; ALKYNES ; SALICYLALDEHYDES ; ALDEHYDES
英文摘要Metal-catalyzed hydroacylation of olefins represents an important atom-economic synthetic process in CH activation. For the first time highly efficient (RhCp)-Cp-III*-catalyzed hydroacylation was realized in the coupling of N-sulfonyl 2-aminobenzaldehydes with both conjugated and aliphatic olefins, leading to the synthesis of various aryl ketones. Occasionally, oxidative coupling occurred when a silver(I) oxidant was used.
语种英语
WOS记录号WOS:000332747400005
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143172
专题中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.South Cent Univ Nationalities, Coll Chem & Mat Sci, Wuhan 430074, Peoples R China
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GB/T 7714
Zhang, Tao,Qi, Zisong,Zhang, Xueyun,et al. Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins[J]. CHEMISTRY-A EUROPEAN JOURNAL,2014,20(12):3283-3287.
APA Zhang, Tao,Qi, Zisong,Zhang, Xueyun,Wu, Lamei,&Li, Xingwei.(2014).Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins.CHEMISTRY-A EUROPEAN JOURNAL,20(12),3283-3287.
MLA Zhang, Tao,et al."Rh-III-Catalyzed Hydroacylation Reactions between N- Sulfonyl 2-Aminobenzaldehydes and Olefins".CHEMISTRY-A EUROPEAN JOURNAL 20.12(2014):3283-3287.
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