DICP OpenIR
Poly(amide-6-b-ethylene oxide)/SAPO-34 mixed matrix membrane for CO2 separation
Zhao, Dan1,2; Ren, Jizhong1; Li, Hui1; Hua, Kaisheng1; Deng, Maicun1
KeywordPebax Sapo-34 Mixed Matrix Membrane Co2 Separation
Source PublicationJOURNAL OF ENERGY CHEMISTRY
2014-03-01
DOI10.1016/S2095-4956(14)60140-6
Volume23Issue:2Pages:227-234
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS Research AreaChemistry ; Energy & Fuels ; Engineering
WOS KeywordPOLY(AMIDE 6-B-ETHYLENE OXIDE) ; SEGMENTED BLOCK-COPOLYMERS ; GAS SEPARATION ; CARBON-DIOXIDE ; COMPOSITE MEMBRANES ; SAPO-34 MEMBRANES ; CO2/CH4 SEPARATIONS ; POLYMERIC MEMBRANES ; INORGANIC FILLERS ; PERMEATION
AbstractIn this paper, poly(amide-6-b-ethylene oxide) (Pebax1657)/SAPO-34 mixed matrix membranes (MMMs) were prepared by solvent-evaporation method with acetic acid as a novel solvent. CO2, N-2, CH4 and H-2 permeation properties were investigated, and the physical properties of Pebax/SAPO-34 MMMs were characterized by XRD and SEM. At low SAPO-34 content, it was homogeneously distributed in the Pebax matrix, and then precipitated and agglomerated at high SAPO-34 content. The crystallinity of Pebax phase in Pebax/SAPO-34 MMMs decreased initially and then rebounded as a result of phase separation. With the increase of transmembrane pressure difference, CO2 permeability was enhanced due to the effect of pressure-induced plasticization. Owing to the happening of stratification, the CO2 permeability of Pebax/SAPO-34 MMMs (50 wt% SAPO-34) increased to 338 Barrer from 111 Barrer of pristine Pebax, while the selectivities of CO2/CH4 and CO2/N-2 were almost unchanged. Compared with the pristine Pebax, the gas separation performances of Pebax/SAPO-34 MMMs were remarkably enhanced.
Language英语
WOS IDWOS:000334145500014
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/143187
Collection中国科学院大连化学物理研究所
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Dan,Ren, Jizhong,Li, Hui,et al. Poly(amide-6-b-ethylene oxide)/SAPO-34 mixed matrix membrane for CO2 separation[J]. JOURNAL OF ENERGY CHEMISTRY,2014,23(2):227-234.
APA Zhao, Dan,Ren, Jizhong,Li, Hui,Hua, Kaisheng,&Deng, Maicun.(2014).Poly(amide-6-b-ethylene oxide)/SAPO-34 mixed matrix membrane for CO2 separation.JOURNAL OF ENERGY CHEMISTRY,23(2),227-234.
MLA Zhao, Dan,et al."Poly(amide-6-b-ethylene oxide)/SAPO-34 mixed matrix membrane for CO2 separation".JOURNAL OF ENERGY CHEMISTRY 23.2(2014):227-234.
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