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MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction
Wang, Fei; Ta, Na; Shen, Wenjie
关键词Mgo Morphology Nanosheets Nanodisks Nanofibers Basic Sites
刊名APPLIED CATALYSIS A-GENERAL
2014-04-05
DOI10.1016/j.apcata.2014.01.026
475页:76-81
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Life Sciences & Biomedicine
类目[WOS]Chemistry, Physical ; Environmental Sciences
研究领域[WOS]Chemistry ; Environmental Sciences & Ecology
关键词[WOS]UNSATURATED ALDEHYDES ; MGO(111) NANOSHEETS ; BIODIESEL SYNTHESIS ; HYDROGEN-TRANSFER ; MAGNESIUM-OXIDE ; REDUCTION ; CATALYSTS ; SURFACE ; 2-PROPANOL ; ETHANOL
英文摘要MgO nanosheets, nanodisks, and nanofibers were synthesized by a hydrothermal method with the aid of suitable surfactants. The nanosheets and nanodisks exposed the (1 1 1) facets mainly whereas the nanofibers exposed a mixture of the (1 1 1), (1 0 0), and (1 1 0) planes. The total number and the surface density of the basic sites followed the order nanosheets > nanodisks > nanofibers. When being used to catalyze the Meerwein-Ponndorf-Verley reaction between benzaldehyde and ethanol, the nanosheets and nanodisks showed much higher reaction rates than the nanofibers, primarily because of their large numbers of surface basic sites that might be linked to the preferential exposure of the {1 1 1} facets. (C) 2014 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000335610400010
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被引频次:32[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143217
专题中国科学院大连化学物理研究所
作者单位Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
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Wang, Fei,Ta, Na,Shen, Wenjie. MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction[J]. APPLIED CATALYSIS A-GENERAL,2014,475:76-81.
APA Wang, Fei,Ta, Na,&Shen, Wenjie.(2014).MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction.APPLIED CATALYSIS A-GENERAL,475,76-81.
MLA Wang, Fei,et al."MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction".APPLIED CATALYSIS A-GENERAL 475(2014):76-81.
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