DICP OpenIR
MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction
Wang, Fei; Ta, Na; Shen, Wenjie
KeywordMgo Morphology Nanosheets Nanodisks Nanofibers Basic Sites
Source PublicationAPPLIED CATALYSIS A-GENERAL
2014-04-05
DOI10.1016/j.apcata.2014.01.026
Volume475Pages:76-81
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences ; Life Sciences & Biomedicine
WOS SubjectChemistry, Physical ; Environmental Sciences
WOS Research AreaChemistry ; Environmental Sciences & Ecology
WOS KeywordUNSATURATED ALDEHYDES ; MGO(111) NANOSHEETS ; BIODIESEL SYNTHESIS ; HYDROGEN-TRANSFER ; MAGNESIUM-OXIDE ; REDUCTION ; CATALYSTS ; SURFACE ; 2-PROPANOL ; ETHANOL
AbstractMgO nanosheets, nanodisks, and nanofibers were synthesized by a hydrothermal method with the aid of suitable surfactants. The nanosheets and nanodisks exposed the (1 1 1) facets mainly whereas the nanofibers exposed a mixture of the (1 1 1), (1 0 0), and (1 1 0) planes. The total number and the surface density of the basic sites followed the order nanosheets > nanodisks > nanofibers. When being used to catalyze the Meerwein-Ponndorf-Verley reaction between benzaldehyde and ethanol, the nanosheets and nanodisks showed much higher reaction rates than the nanofibers, primarily because of their large numbers of surface basic sites that might be linked to the preferential exposure of the {1 1 1} facets. (C) 2014 Elsevier B.V. All rights reserved.
Language英语
WOS IDWOS:000335610400010
Citation statistics
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/143217
Collection中国科学院大连化学物理研究所
AffiliationChinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
Recommended Citation
GB/T 7714
Wang, Fei,Ta, Na,Shen, Wenjie. MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction[J]. APPLIED CATALYSIS A-GENERAL,2014,475:76-81.
APA Wang, Fei,Ta, Na,&Shen, Wenjie.(2014).MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction.APPLIED CATALYSIS A-GENERAL,475,76-81.
MLA Wang, Fei,et al."MgO nanosheets, nanodisks, and nanofibers for the Meerwein-Ponndorf-Verley reaction".APPLIED CATALYSIS A-GENERAL 475(2014):76-81.
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