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学科主题物理化学
Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst
Zhang, Junying1,2; Hou, Baolin1; Wang, Xuefei3; Li, Zhenlei1,2; Wang, Aiqin1; Zhang, Tao1; Wang AQ(王爱琴); Zhang T(张涛)
关键词Glucose Hydrogenation Binary Catalyst System Suppressing Effect Retro-aldol Condensation Ethylene Glycol Tungstic Compounds Ru/c Catalyst
刊名JOURNAL OF ENERGY CHEMISTRY
2015
DOI10.1016/S2095-4956(15)60278-9
24期:1页:9-14
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences ; Technology
类目[WOS]Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
研究领域[WOS]Chemistry ; Energy & Fuels ; Engineering
关键词[WOS]ETHYLENE-GLYCOL PRODUCTION ; 1,2-PROPYLENE GLYCOL ; RUTHENIUM CATALYST ; CARBIDE CATALYSTS ; RENEWABLE DIESEL ; CONVERSION ; CELLULOSE ; CHEMICALS ; BIOMASS ; ACID
英文摘要The effect of acid component including various conventional acids and tungstic compounds on glucose hydrogenation over a series of binary catalyst system containing Ru/C catalyst was investigated. The results showed that HCl, H2SO4, H3BO3, H3PO4, and HNO3 had negligible effect, while all the tungstic compounds imposed inhibiting effects on the hydrogenation of glucose over Ru/C catalyst, and the suppressing effect followed the order of H2WO4>HPW>WO3>AMT>HSiW. This order is the same as the order of ethylene glycol (EG) yields in the one-pot conversion of glucose to EG, suggesting the important role of competition between glucose hydrogenation and retro-aldol condensation in controlling the selectivity of EG.
语种英语
WOS记录号WOS:000350785000002
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/143798
专题中国科学院大连化学物理研究所
通讯作者Wang AQ(王爱琴); Zhang T(张涛)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Beijing Univ Chem Technol, Coll Sci, Beijing 100029, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Junying,Hou, Baolin,Wang, Xuefei,et al. Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst[J]. JOURNAL OF ENERGY CHEMISTRY,2015,24(1):9-14.
APA Zhang, Junying.,Hou, Baolin.,Wang, Xuefei.,Li, Zhenlei.,Wang, Aiqin.,...&张涛.(2015).Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst.JOURNAL OF ENERGY CHEMISTRY,24(1),9-14.
MLA Zhang, Junying,et al."Inhibiting effect of tungstic compounds on glucose hydrogenation over Ru/C catalyst".JOURNAL OF ENERGY CHEMISTRY 24.1(2015):9-14.
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