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学科主题: 物理化学
题名: Nanostructured Proton Conductors Formed via in Situ Polymerization of Ionic Liquid Crystals
作者: Lu, Fei1;  Gao, Xinpei1;  Doug, Bin2;  Sun, Panpan1;  Sun, Nan1;  Xie, Shuting1;  Zheng, Liqiang1
通讯作者: LiqiangZheng
关键词: ionic liquid crystals ;  zwitterions ;  photopolymerization ;  proton-conductors ;  self-assembly
刊名: ACS APPLIED MATERIALS & INTERFACES
发表日期: 2014-12-24
DOI: 10.1021/am504504m
卷: 6, 期:24, 页:21970-21977
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Technology
类目[WOS]: Nanoscience & Nanotechnology ;  Materials Science, Multidisciplinary
研究领域[WOS]: Science & Technology - Other Topics ;  Materials Science
英文摘要: Ionic liquid crystals (ILCs) with hexagonal and lamellar phases were successfully fabricated by the self-assembly of a polymerizable amphiphilic zwitterion, which is formed by 3-(1-vinyl-3-imidazolio)propanesulfonate (VIPS) and 4-dodecyl benzenesulfonic acid (DBSA) based on intermolecular electrostatic interactions. The microstructures and phase behaviors of ILCs were studied by polarized microscope (POM) and small-angle X-ray scattering (SAXS). The ILC topological structures can be considered as proton pathways and further fixed by photopolymerization to prepare nanostructured proton-conductive films. The introduction of highly ordered and well-defined ILC structures into these polymeric films radically improves the ionic conductivities.
关键词[WOS]: SELF-ORGANIZATION ;  TERNARY MIXTURES ;  FUEL-CELLS ;  MEMBRANES ;  CONDUCTIVITY ;  PHASES ;  TRANSPORT ;  ELECTROLYTE ;  ZWITTERIONS ;  WATER
语种: 英语
WOS记录号: WOS:000347139400028
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/143802
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China

Recommended Citation:
Lu, Fei,Gao, Xinpei,Doug, Bin,et al. Nanostructured Proton Conductors Formed via in Situ Polymerization of Ionic Liquid Crystals[J]. ACS APPLIED MATERIALS & INTERFACES,2014,6(24):21970-21977.
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