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学科主题: 物理化学
题名: Significantly enhanced dehydrogenation properties of calcium borohydride combined with urea
作者: Chu, Hailiang1, 2;  Qiu, Shujun2;  Liu, Lin;  Zou, Yongjin1, 2;  Xiang, Cuili2;  Zhang, Huanzhi2;  Xu, Fen2;  Sun, Lixian2;  Zhou, Huaiying2;  Wu, Guotao1
通讯作者: 吴国涛 ;  HailiangChu
刊名: DALTON TRANSACTIONS
发表日期: 2014
DOI: 10.1039/c4dt01355g
卷: 43, 期:41, 页:15291-15294
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Inorganic & Nuclear
研究领域[WOS]: Chemistry
英文摘要: The interaction of [BHx]- and [NHx]-containing species gives rise to molecular hydrogen and the establishment of the B-N bond. Up to now, metal amides and ammonia are the commonly used [NHx] sources. Herein, urea, an organic carbonyl diamide, was used to react with Ca(BH4)(2). A new type of complex hydride Ca(BH4)(2)center dot 4CO(NH2)(2) was synthesized with release of ca. 5.2 wt% hydrogen below 250 degrees C.
关键词[WOS]: HYDROGEN STORAGE PROPERTIES ;  LITHIUM HYDRIDE ;  CA(BH4)(2) ;  AMIDOBORANES ;  SYSTEM ;  BORANE ;  STATE
语种: 英语
WOS记录号: WOS:000342757600005
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/143964
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Guilin Univ Elect Technol, Sch Mat Sci & Engn, Guilin 541004, Peoples R China

Recommended Citation:
Chu, Hailiang,Qiu, Shujun,Liu, Lin,et al. Significantly enhanced dehydrogenation properties of calcium borohydride combined with urea[J]. DALTON TRANSACTIONS,2014,43(41):15291-15294.
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