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学科主题: 物理化学
题名: Efficient fixation of CO2 at mild conditions by a Cr-conjugated microporous polymer
作者: Xie, Yong1, 2;  Yang, Rui-Xia2;  Huang, Nian-Yu1;  Luo, Hua-Jun1;  Deng, Wei-Qiao2
通讯作者: 邓伟侨
关键词: carbon dioxide ;  epoxides ;  cyclic carbonate ;  polymer ;  capture capacity
刊名: JOURNAL OF ENERGY CHEMISTRY
发表日期: 2014
DOI: 10.1016/S2095-4956(14)60113-3
卷: 23, 期:1, 页:22-28
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences ;  Technology
类目[WOS]: Chemistry, Applied ;  Chemistry, Physical ;  Energy & Fuels ;  Engineering, Chemical
研究领域[WOS]: Chemistry ;  Energy & Fuels ;  Engineering
英文摘要: We reported a bifunctional material, Cr-salen implanted conjugated microporous polymer (Cr-CMP), which is able to capture excellent CO2 amounts and has a remarkable catalytic activity towards the cycloaddition reaction of CO2 to epoxides forming cyclic carbonates at mild conditions without additional solvents. This heterogeneous Cr-CMP catalyst has a superior catalytic activity to its related homogeneous catalyst and can be reused more than ten times without a significant decrease in catalytic activity.
关键词[WOS]: HIGH-SURFACE-AREA ;  CYCLIC CARBONATES ;  HETEROGENEOUS CATALYST ;  PROPYLENE CARBONATE ;  ORGANIC CARBONATES ;  ETHYLENE CARBONATE ;  EPOXIDES ;  COMPLEXES ;  NETWORKS ;  DIOXIDE
语种: 英语
WOS记录号: WOS:000331667500004
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/143981
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.China Three Gorges Univ, Coll Chem & Life Sci, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Hubei, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Xie, Yong,Yang, Rui-Xia,Huang, Nian-Yu,et al. Efficient fixation of CO2 at mild conditions by a Cr-conjugated microporous polymer[J]. JOURNAL OF ENERGY CHEMISTRY,2014,23(1):22-28.
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