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学科主题物理化学
Low-energy photoelectron imaging of HS2 anion
Qin, Zhengbo1,2; Cong, Ran2; Liu, Zhiling1; Xie, Hua1; Tang, Zichao1; Tang ZC(唐紫超)
刊名JOURNAL OF CHEMICAL PHYSICS
2014-11-28
DOI10.1063/1.4901978
141期:20页:204312
收录类别SCI
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Physics, Atomic, Molecular & Chemical
研究领域[WOS]Physics
关键词[WOS]HYDROGEN-SULFIDE ; OXYGEN-ATOMS ; THERMOCHEMISTRY ; SPECTROSCOPY ; MOLECULES ; KINETICS ; SPECTRA ; DENSITY ; PHOTODETACHMENT ; THRESHOLD
英文摘要Low-energy photoelectron imaging of HS2- has been investigated, which provides the vibrational frequencies of the ground state as well as the first excited state of HS2. It allows us to determine more accurate electron affinity of HS2, 1.9080 +/- 0.0018 eV. Combined with Frank-Condon simulation, the vibrational features have been unveiled related to S-S stretching and S-S-H bending modes for the ground state and S-S stretching, S-S-H bending, and S-H stretching modes for the first excited state. Photoelectron angular distributions are mainly characteristic of electron detachment from two different molecular orbitals (MOs) in HS2-. With the aid of accurate electron affinity value of HS2, corresponding thermochemical quantities can be accessed. (C) 2014 AIP Publishing LLC.
语种英语
WOS记录号WOS:000345641400022
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144065
专题中国科学院大连化学物理研究所
通讯作者Tang ZC(唐紫超)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Anhui Normal Univ, Dept Phys, Wuhu 241000, Anhui, Peoples R China
推荐引用方式
GB/T 7714
Qin, Zhengbo,Cong, Ran,Liu, Zhiling,et al. Low-energy photoelectron imaging of HS2 anion[J]. JOURNAL OF CHEMICAL PHYSICS,2014,141(20):204312.
APA Qin, Zhengbo,Cong, Ran,Liu, Zhiling,Xie, Hua,Tang, Zichao,&唐紫超.(2014).Low-energy photoelectron imaging of HS2 anion.JOURNAL OF CHEMICAL PHYSICS,141(20),204312.
MLA Qin, Zhengbo,et al."Low-energy photoelectron imaging of HS2 anion".JOURNAL OF CHEMICAL PHYSICS 141.20(2014):204312.
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