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学科主题: 物理化学
题名: Direct reductive amination of 5-hydroxymethylfurfural with primary/secondary amines via Ru-complex catalyzed hydrogenation
作者: Xu, Zhanwei1;  Yan, Peifang1;  Xu, Wenjuan1;  Jia, Songyan1;  Xia, Zhi1;  Chung, Benjamin1;  Zhang, Z. Conrad1
通讯作者: 张宗超
刊名: RSC ADVANCES
发表日期: 2014
DOI: 10.1039/c4ra10349a
卷: 4, 期:103, 页:59083-59087
收录类别: SCI
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: In this work, the complex dichlorobis(2,9-dimethyl-1,10-phenanthroline)ruthenium(II) (Ru(DMP)(2)Cl-2) was found to effectively catalyze the direct reductive amination of bio-based 5-hydroxymethylfurfural (5-HMF) in the presence of H-2 (g) in ethanol solvent. Good product yields (66-95%) were obtained from a broad substrate scope of primary and secondary amines.
关键词[WOS]: MONONUCLEAR RUTHENIUM(II) COMPLEXES ;  GAMMA-VALEROLACTONE ;  RENEWABLE RESOURCES ;  LEVULINIC ACID ;  BIOMASS ;  TRANSFORMATION ;  CONVERSION ;  FUELS ;  METHYLATION ;  OXIDATION
语种: 英语
WOS记录号: WOS:000345652300021
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144071
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian, Peoples R China

Recommended Citation:
Xu, Zhanwei,Yan, Peifang,Xu, Wenjuan,et al. Direct reductive amination of 5-hydroxymethylfurfural with primary/secondary amines via Ru-complex catalyzed hydrogenation[J]. RSC ADVANCES,2014,4(103):59083-59087.
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