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学科主题物理化学
Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles
Wu, Kaikai1; Wu, Ping1; Wang, Liandi1; Chen, Jiping1; Sun, Chenglin1; Yu, Zhengkun1,2; Yu ZK(余正坤)
关键词Alkenylation Alkylation Bronsted Acids 3-(Dimethylamino)Acrylonitrile Indoles
刊名ADVANCED SYNTHESIS & CATALYSIS
2014-12-15
DOI10.1002/adsc.201400477
356期:18页:3871-3880
收录类别SCI ; IC
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Applied ; Chemistry, Organic
研究领域[WOS]Chemistry
关键词[WOS]C-H ACTIVATION ; BOND ACTIVATION ; PRACTICAL SYNTHESIS ; FUNCTIONALIZATION ; ALKENES ; C2-ALKENYLATION ; 2-ALKYLATION ; DERIVATIVES ; OLEFINATION ; ALDEHYDES
英文摘要The Bronsted acid-mediated alkylation and alkenylation of indoles were efficiently achieved by means of 3-(dimethylamino)acrylonitrile. Regulating the acidity of the reaction medium with para-toluenesulfonic acid monohydrate (p-TsOH center dot H2O) and/or acetic acid (HOAc) led to versatile formation of 3-alkylated and 3-alkenylated indole derivatives under mild conditions. The 3-alkylated indole products could be nearly quantitatively transformed to the corresponding separable (E)- and (Z)-3-alkenylated indoles.
语种英语
WOS记录号WOS:000346071600020
引用统计
文献类型期刊论文
条目标识符http://cas-ir.dicp.ac.cn/handle/321008/144082
专题中国科学院大连化学物理研究所
通讯作者Yu ZK(余正坤)
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
推荐引用方式
GB/T 7714
Wu, Kaikai,Wu, Ping,Wang, Liandi,et al. Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles[J]. ADVANCED SYNTHESIS & CATALYSIS,2014,356(18):3871-3880.
APA Wu, Kaikai.,Wu, Ping.,Wang, Liandi.,Chen, Jiping.,Sun, Chenglin.,...&余正坤.(2014).Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles.ADVANCED SYNTHESIS & CATALYSIS,356(18),3871-3880.
MLA Wu, Kaikai,et al."Tunable Bronsted Acidity-Dependent Alkylation and Alkenylation of Indoles".ADVANCED SYNTHESIS & CATALYSIS 356.18(2014):3871-3880.
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