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学科主题: 物理化学
题名: Asymmetric Hydrogenation via Capture of Active Intermediates Generated from Aza-Pinacol Rearrangement
作者: Yu, Chang-Bin1;  Huang, Wen-Xue1;  Shi, Lei1;  Chen, Mu-Wang1;  Wu, Bo1;  Zhou, Yong-Gui1, 2
通讯作者: 周永贵
刊名: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
发表日期: 2014-11-12
DOI: 10.1021/ja5075745
卷: 136, 期:45, 页:15837-15840
收录类别: SCI ;  IC ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Multidisciplinary
研究领域[WOS]: Chemistry
英文摘要: An efficient palladium-catalyzed asymmetric hydrogenation via capture of an active intermediate generated in situ from acid-catalyzed aza-Pinacol rearrangement has been successfully developed, providing efficient access to chiral exocyclic amines with up to 98% ee. Three-, four-, and five-membered cyclic N-sulfonyl amino alcohols are viable substrates. This study opens a new window to the application of asymmetric hydrogenation.
关键词[WOS]: C BOND FORMATION ;  RUTHENIUM-CATALYZED HYDROHYDROXYALKYLATION ;  ALDEHYDE OXIDATION LEVEL ;  SEMIPINACOL REARRANGEMENT ;  ENANTIOSELECTIVE APPROACH ;  FORMING HYDROGENATION ;  ALLYLIC ALCOHOLS ;  BRONSTED ACIDS ;  FACILE ACCESS ;  IMINES
语种: 英语
WOS记录号: WOS:000344906100008
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144100
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

Recommended Citation:
Yu, Chang-Bin,Huang, Wen-Xue,Shi, Lei,et al. Asymmetric Hydrogenation via Capture of Active Intermediates Generated from Aza-Pinacol Rearrangement[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2014,136(45):15837-15840.
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