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学科主题: 物理化学
题名: Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols
作者: Wang, Qingfu1;  Du, Wangming1;  Liu, Tingting1;  Chai, Huining1;  Yu, Zhengkun1
通讯作者: 余正坤
关键词: Ruthenium(II) ;  Pyridyl-imidazolyl-pyrazolyl ligand ;  Oppenauer oxidation ;  Secondary alcohols
刊名: TETRAHEDRON LETTERS
发表日期: 2014-02-26
DOI: 10.1016/j.tetlet.2014.01.072
卷: 55, 期:9, 页:1585-1588
收录类别: SCI ;  CCR
文章类型: Article
WOS标题词: Science & Technology ;  Physical Sciences
类目[WOS]: Chemistry, Organic
研究领域[WOS]: Chemistry
英文摘要: Highly efficient Oppenauer-type oxidation of secondary alcohols to the corresponding ketones has been realized by means of the ruthenium(II) complex catalysts bearing a 2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine ligand. The oxidation reaction underwent in the presence of acetone as oxidant under mild conditions, reaching final TOF values up to 3960 h(-1). The hemilability of the ligand is attributed to the high catalytic activity of these Ru(II) complexes. (c) 2014 Elsevier Ltd. All rights reserved.
关键词[WOS]: ASYMMETRIC TRANSFER HYDROGENATION ;  HETEROCYCLIC CARBENE COMPLEXES ;  PYRAZOLYL-IMIDAZOLYL LIGAND ;  ROOM-TEMPERATURE ;  KETONES ;  BEARING ;  MECHANISM ;  PEROXIDE ;  HYDRIDE ;  GREEN
语种: 英语
WOS记录号: WOS:000332434000018
Citation statistics: 
内容类型: 期刊论文
URI标识: http://cas-ir.dicp.ac.cn/handle/321008/144204
Appears in Collections:中国科学院大连化学物理研究所_期刊论文

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作者单位: 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China

Recommended Citation:
Wang, Qingfu,Du, Wangming,Liu, Tingting,et al. Ruthenium(II)-NNN complex catalyzed Oppenauer-type oxidation of secondary alcohols[J]. TETRAHEDRON LETTERS,2014,55(9):1585-1588.
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