DICP OpenIR
Subject Area物理化学
High-performance hydrogen evolution electrocatalysis by layer-controlled MoS2 nanosheets
Deng, Jiao1; Yuan, Wentao2; Ren, Pengju1; Wang, Yong2; Deng, Dehui1; Zhang, Ze2; Bao, Xinhe1; Deng DH(邓德会)
Source PublicationRSC ADVANCES
2014
DOI10.1039/c4ra05614k
Volume4Issue:66Pages:34733-34738
Indexed BySCI
SubtypeArticle
WOS HeadingsScience & Technology ; Physical Sciences
WOS SubjectChemistry, Multidisciplinary
WOS Research AreaChemistry
WOS KeywordACTIVE EDGE SITES ; TRANSITION-METAL DICHALCOGENIDES ; 2-DIMENSIONAL NANOSHEETS ; ULTRATHIN NANOSHEETS ; MOLYBDENUM SULFIDE ; RAMAN-SCATTERING ; GRAPHENE ; NANOPARTICLES ; NANOTUBES ; EFFICIENT
AbstractHydrogen is considered as an important clean energy carrier for the future, and electrocatalytic splitting of water is one of the most efficient technologies for hydrogen production. As a potential alternative to Pt-based catalysts in hydrogen evolution reaction (HER), two-dimensional (2D) molybdenum sulfide (MoS2) nanomaterials have attracted enormous research interest, while the structure control for high-performance HER electrocatalysis remains a considerable challenge due to the lack of efficient preparation techniques. Herein, we reported a one-pot chemical method to directly synthesize 2D MoS2 with controllable layers. Multiple-layer MoS2 (ML-MoS2), few-layer MoS2 (FL-MoS2) and single-layer MoS2 coating on carbon nanotubes (SL-MoS2-CNTs) can be efficiently prepared through the modulation of experimental conditions. The enhanced catalytic activity in HER is demonstrated by reducing the layer number of MoS2 nanosheets. Remarkably, the optimized SL-MoS2-CNTs sample showed long-term durabilitywith an accelerated degradation experiment even after more than 10 000 recycles, and high HER activity with an onset over-potential of only similar to 40 mV vs. RHE. This study introduces a novel, cheap and facile strategy to prepare layer-controlled 2D MoS2 nanosheets in a large quantity, and is expected to broaden the already wide range energy applications of 2D MoS2 nanosheets.
Language英语
WOS IDWOS:000341287700002
Citation statistics
Cited Times:35[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://cas-ir.dicp.ac.cn/handle/321008/144206
Collection中国科学院大连化学物理研究所
Corresponding AuthorDeng DH(邓德会)
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
Recommended Citation
GB/T 7714
Deng, Jiao,Yuan, Wentao,Ren, Pengju,et al. High-performance hydrogen evolution electrocatalysis by layer-controlled MoS2 nanosheets[J]. RSC ADVANCES,2014,4(66):34733-34738.
APA Deng, Jiao.,Yuan, Wentao.,Ren, Pengju.,Wang, Yong.,Deng, Dehui.,...&邓德会.(2014).High-performance hydrogen evolution electrocatalysis by layer-controlled MoS2 nanosheets.RSC ADVANCES,4(66),34733-34738.
MLA Deng, Jiao,et al."High-performance hydrogen evolution electrocatalysis by layer-controlled MoS2 nanosheets".RSC ADVANCES 4.66(2014):34733-34738.
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2014ITtHFM2bdz.PDF(4044KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
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